IP Library Granted Patent US 8,312,927
Granted Patent B2
US 8,312,927 · App. 12/421,289 · Granted Nov 20, 2012

Apparatus and methods for adjusting operational parameters to recover hydrocarbonaceous and additional products from oil shale and sands

Assignee: General Synfuels International, Inc.
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Quick Facts
Patent No.
US 8,312,927
App. No.
12/421,289
Granted
Nov 20, 2012
Kind
B2
Abstract

Apparatus and methods are described for recovering hydrocarbonaceous and additional products from nonrubilized oil shale and oil/tar sands. One or more initial condensation steps are performed to recover crude-oil products from the effluent gas, followed by one or more subsequent condensation steps to recover additional, non-crude-oil products. The effluent gas is maintained under a negative pressure from the hole and through the initial and subsequent condensation steps. This provides numerous advantages, including the adjustment of various physical parameters during the extraction process. Such adjustment allows the ratio of oils types to be varied, the ratio of hydrocarbonaceous products to non-crude products to be varied, contamination control, and other disclosed advantages.

Claims (84)

1. A method of recovering hydrocarbonaceous and other products from non-rubbilized oil shale and oil/tar sands, comprising the steps of:

forming a hole in a body of the oil shale or sand;

positioning a gas inlet conduit into the hole;

heating and pressurizing a processing gas;

introducing the processing gas into the hole through the gas inlet conduit, thereby creating a nonburning thermal energy front sufficient to convert kerogen in oil shale or bitumen in oil sand to hydrocarbonaceous products;

withdrawing the processing gas and hydrocarbonaceous products as effluent gas through the hole;

performing first and second initial condensation steps to separately recover and store heavy and sweet crude oil products from the effluent gas;

performing one or more subsequent condensation steps to recover and store additional liquefied products from the effluent gas; and

maintaining the effluent gas under a negative pressure from the hole and through the initial and subsequent condensation steps.

2. The method of claim 1 , wherein the step of performing one or more subsequent condensation steps includes the recovery and storage of one or more of the following additional products:

liquefied ethane,

liquefied propane,

liquefied butane,

liquefied carbon dioxide,

liquefied methane,

liquefied nitrogen, and

hydrogen.

3. The method of claim 1 , including the steps of:

burning a fuel that produces an exhaust gas and heat within a heat exchanger; and

routing the exhaust gas through the heat exchanger to create the processing gas.

4. The method of claim 1 , including the steps of:

burning a fuel that produces an exhaust gas and heat within a heat exchanger;

mixing at least one of the additional products with the exhaust gas; and

routing the mixture through the heat exchanger to create the processing gas.

5. The method of claim 1 , including the step of controlling the composition of the processing gas is oxygen-deprived.

6. The method of claim 1 , including the step of controlling the composition of the processing gas so that it contains approximately 1% oxygen or less.

7. The method of claim 1 , including the steps of:

performing the subsequent condensation steps in at least one cooled chamber having an input and an output; and

providing a compressor system at the output of the cooled chamber to maintain the effluent gas at a negative pressure from the hole and through the initial and subsequent condensation steps.

8. The method of claim 1 , including the step of performing the subsequent condensation steps in at least one cooled chamber having an input, an output, and a plurality of critical orifices sized to recover the other products.

9. The method of claim 1 , wherein:

one of the other products is liquid carbon dioxide; and

the subsequent condensation steps are performed in a chamber cooled with the liquid carbon dioxide.

10. The method of claim 1 , wherein:

one of the other products is liquid carbon dioxide; and

the subsequent condensation steps are performed in a chamber cooled with the liquid carbon dioxide and including critical orifices sized to recover the other products.

11. The method of claim 1 wherein, in oil shale, the step of withdrawing the processing gas and hydrocarbonaceous products as effluent gas through the hole is sufficient to withdraw at least a portion of the hydrocarbonaceous products from the shale through the Venturi effect.

12. The method of claim 1 , further including the steps of:

forming a plurality of holes, each with a gas inlet to receive a heated and pressurized processing gas;

withdrawing the processing gas and hydrocarbonaceous products as effluent gas through each hole; and

performing a plurality of condensation steps to recover crude oil products and additional products from the effluent gas from a plurality of the holes.

13. The method of claim 1 , wherein the crude oil is obtained as a ratio of heavy crude to lighter crudes, the method further including the step of reducing the flow rate of the processing gas to reduce the ratio.

14. The method of claim 1 , wherein the crude oil is obtained as a ratio of heavy crude to lighter crudes, the method further including the step of increasing the reflux time of the heavy crude with respect to the initial condensation step to reduce the ratio.

15. The method of claim 1 , including the step of adjusting one or more of the following parameters to vary the recovery of crude oil, other products or contaminants from the effluent gas:

the temperature, pressure or flow rate of the processing gas,

the residency time of the processing gas in the hole,

the reflux time of the crude oil with respect to the initial condensation step.

16. The method of claim 1 , including the step of providing an apertured sleeve within the hole to extract hydrocarbonaceous products from oil/tar sands.

17. A system for recovering hydrocarbonaceous and other products from a hole drilled in non-rubbilized oil shale and oil/tar sands, the system comprising:

a combustor for heating and pressurizing a processing gas;

a gas inlet conduit for introducing the processing gas into the hole to convert kerogen in oil shale or bitumen in oil sand into hydrocarbonaceous products;

a gas outlet conduit for withdrawing the processing gas and hydrocarbonaceous products from the hole;

an initial condenser system for separately recovering heavy and sweet crude oil products from the effluent gas;

one or more tanks for storing the recovered crude oil products;

a subsequent condenser system for recovering additional products from the effluent gas;

one or more tanks for storing the recovered additional products; and

a compressor for maintaining the effluent gas under a negative pressure from the hole and through the condenser systems.

18. The system of claim 17 , wherein the subsequent condenser system is operative to recover of one or more of the following additional products:

liquefied ethane,

liquefied propane,

liquefied butane,

liquefied carbon dioxide,

liquefied methane,

liquefied nitrogen, and

hydrogen.

19. The system of claim 17 , wherein:

the combustor produces an exhaust gas, the system further including a heat exchanger heated by the combustor; and

the processing gas is generated by heating the exhaust gas with the heat exchanger.

20. The system of claim 17 , wherein the combustor produces an exhaust gas, the system further including:

one or more conduits for routing the at least one of the additional products with the exhaust gas; and

the processing gas is generated by heating the mixture of the exhaust gas and the additional products with the heat exchanger.

21. The system of claim 17 , wherein the subsequent condenser system includes:

a cooled chamber; and

a plurality of conduit loops within the chamber, each followed by a critical orifice, each loop and following critical orifice being physically configured to condense a different one of the additional products.

22. The system of claim 17 , wherein the subsequent condenser system includes:

a cooled chamber;

a plurality of conduit loops within the chamber, each followed by a critical orifice, each loop and following critical orifice being physically configured to condense a different one of the additional products; and

wherein one of the additional products is liquefied carbon dioxide which is used to cool the chamber.

23. The system of claim 17 , further including:

a plurality of gas inlet conduits, each situated in a separately drilled hole;

a plurality of gas outlet conduits, each withdrawing the processing gas and hydrocarbonaceous products as effluent gas through a respective one of the holes; and

wherein the condenser systems are fed by a plurality of the gas outlet conduits.

24. The system of claim 17 , wherein the initial condenser system includes a reflux chamber to reduce the ratio of heavy crude to lighter crudes.

25. The system of claim 17 , wherein the gas outlet conduit is in gaseous communication with an apertured sleeve disposed within the hole to extract hydrocarbonaceous products from oil/tar sands.

Assignments (4)
SECURITY INTEREST Recorded Jan 14, 2015
From: GENERAL SYNFUELS INTERNATIONAL, INC.
To: MALONE, ANDREW H; THE JANET HUGHES MORROW 1992 TRUST, FBO JANET HUGHES MORROW
Reel/Frame 034707/0861 →
SECURITY AGREEMENT Recorded Oct 28, 2010
From: GENERAL SYNFUELS INTERNATIONAL, INC.
To: MTERRA VENTURES LLC
Reel/Frame 025204/0311 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 14, 2009
From: LOCKART, MICHAEL D.; MCQUEEN, RON
To: GENERAL SYNFUELS INTERNATIONAL, INC.
Reel/Frame 022524/0084 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 10, 2009
From: LOCKHART, MICHAEL D.; MCQUEEN, RON
To: GENERAL SYNFUELS INTERNATIONAL, INC.
Reel/Frame 022513/0369 →
Continuity (1)
Related Publication 20100258316A1 · Oct 14, 2010