Porous, dissolvable solid substrate and a surface resident coating of cationic surfactant conditioner
The present invention relates to hair care compositions, especially those hair care compositions in the form of a hair care article that is a porous dissolvable solid substrate. The porous dissolvable solid substrate has a surface resident coating comprising the cationic surfactant conditioner active that can provide a conditioning benefit.
1. A hair care article comprising:
a.) a porous dissolvable solid substrate comprising:
i. from about 10% to about 75% by weight of an anionic surfactant;
ii. from about 10% to about 50% by weight of a water-soluble polymer;
iii. from about 1% to about 30% by weight of a plasticizer; and
b.) a surface resident coating comprising from about 10% to about 100% by weight of one or more cationic surfactant conditioner actives;
wherein the weight ratio of the porous dissolvable solid substrate to the surface resident coating is from about 110:1 to about 0.5:1, and
wherein the porous dissolvable solid substrate comprises a percent open cell content from about 80% to about 100.0%.
2. The hair care article of claim 1 , wherein the weight ratio of the porous dissolvable solid substrate to the surface resident coating is from about 20:1 to about 1:1.
3. The hair care article of claim 1 , wherein the weight ratio of the porous dissolvable solid substrate to the surface resident coating is from about 10:1 to about 1.5:1.
4. The hair care article of claim 1 , wherein the weight ratio of the porous dissolvable solid substrate to the surface resident coating is from about 7:1 to about 3:1.
5. The hair care article of claim 1 , wherein the surface resident coating comprising the cationic surfactant conditioner active is a powder.
6. The hair care article of claim 1 , wherein the cationic conditioner active is selected from alkyl quaternary ammonium salts, alkyl amine salts, and mixtures thereof.
7. The hair care article of claim 1 , wherein the cationic conditioner active is an alkyl quaternary ammonium salt having the Formula I:
wherein R 1 , R 2 , R 3 , and R 4 are each independently selected from the group consisting of an aliphatic group of from 1 to 22 carbon atoms, or an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alkylaryl group having up to 22 carbon atoms; and
wherein X is a salt-forming anion selected from the group consisting of halogen, acetate, citrate, lactate, glycolate, phosphate, nitrate, sulphate, alkylsulphate radicals, and combinations thereof.
8. The hair care article of claim 7 , comprising the alkyl quaternary ammonium salt of Formula I, wherein R 1 and R 2 are each independently selected from the group consisting of C 16 to C 22 hydrocarbyl chains comprising at least one ester linkage in both R 1 and R 2 , and R 1 and R 2 are each independently selected from C 16 to C 22 saturated or unsaturated chains, and wherein R 3 and R 4 are each independently selected from CH 3 and CH 2 CH 2 OH.
9. The hair care article of claim 1 , wherein the cationic conditioner active is an alkyl amine salt corresponding to alkyl amines having the Formula II:
R 1 —C(O)—N(H)—R 2 —N(R 3 )(R 4 )
wherein R 1 is a fatty acid chain containing from 12 to 22 carbon atoms, R 2 is an alkylene group containing from one to four carbon atoms, and R 3 and R 4 are, independently, an alkyl group having from one to four carbon atoms.
10. The hair care article of claim 9 , wherein the alkyl amine salt is the salt corresponding to alkyl amines having the Formula II neutralized with acids selected from the group consisting of hydrochloric acid, sulphuric acid, nitric acid, phosphoric acid, lactic acid, citric acid, tartaric acid, acetic acid, gluconic acid, glycolic acid and propionic acid, and combinations thereof.
11. The hair care article of claim 1 , wherein the surface resident coating comprising the cationic surfactant conditioner active is in the of a layer.
12. The hair care article of claim 1 , wherein the surface resident coating comprising the cationic surfactant conditioner active is attached to at least a portion of the outer surface of the porous dissolvable solid substrate.
13. The hair care article of claim 1 , wherein the surface resident coating comprising the cationic surfactant conditioner active covers the outer surface of the porous dissolvable solid substrate.
14. The hair care article of claim 1 , wherein the dissolvable hair care article comprises two porous dissolvable solid substrates, and wherein the surface resident coating comprising the cationic surfactant conditioner active is a layer situated between the two porous dissolvable solid substrates.
15. The hair care article of claim 1 , wherein the porous dissolvable solid substrate having a basis weight of from about 125 grams/m 2 to about 3,000 grams/m 2 and a thickness of from about 0.5 mm to about 10 mm.
16. The hair care article of claim 1 , wherein the porous dissolvable solid substrate comprises a specific surface area from about 0.03 m 2 /gram to about 0.25m 2 /gram.
17. The hair care article of claim 1 , wherein the porous dissolvable solid substrate comprises a cell wall thickness of from about 0.02 mm to about 0.15 mm.
18. The hair care article of claim 1 , wherein the hair care article comprises one or more water-soluble polymers selected from the group consisting of polyvinyl alcohols, polyacrylates, copolymers of acrylic acid and methacrylic acid, polyvinylpyrrolidones, polyalkylene oxides, starch and starch derivatives, pullulan, gelatin, hydroxypropylmethylcelluloses, methylcelluloses, and carboxymethycelluloses.
19. The hair care article of claim 1 , wherein the hair care article comprises a plasticizer selected from the group consisting of polyols, copolyols, polycarboxylic acids, polyesters, and dimethicone copolyols.
20. The hair care article of claim 1 , wherein the coating further comprises an additional component selected from the group consisting of a starch perfume matrix microsphere, a perfume loaded inorganic absorbent powder, a beta cyclodextrin encapsulated perfume, any other perfume active, an inactive starch composition, and any combination thereof.
21. A method for making a hair care article, the method comprising
applying a surface resident coating comprising the cationic surfactant conditioner active in powdered form to a porous dissolvable solid substrate comprising
from about 10% to about 75% by weight of an anionic surfactant,
from about 10% to about 50% by weight of a water-soluble polymer, and
from about 1% to about 30% by weight of a plasticizer.
22. A method for making a hair care article, the method comprising:
(a) preparing a processing mixture comprising from about 5% to about 50% by weight of a surfactant wherein the surfactant is selected from the group consisting of from about 0 to about 10% by weight of an anionic surfactant, non-ionic surfactant, polymeric surfactant, and combinations thereof, from about 5% to about 35% by weight of a water-soluble polymer, and from about 0.5% to about 20% by weight of a plasticizer;
(b) aerating the processing mixture by introducing a gas into the processing mixture to form an aerated wet mixture;
(c) forming the aerated wet mixture into one or more desired shapes;
(d) drying the aerated wet mixture to form a porous dissolvable solid substrate;
and; (e) applying a surface resident coating comprising the cationic surfactant conditioner active in powdered form to the porous dissolvable solid substrate.
23. The method of making a hair care article according to claim 22 , wherein the surface resident coating comprising the cationic surfactant conditioner active is applied to the porous dissolvable solid substrate at a humidity of about 20% to about 70%.
24. The method of making a hair care article according to claim 22 , wherein the surface resident coating comprising the cationic surfactant conditioner active is applied to the porous dissolvable solid substrate at a humidity of about 30% to about 60%.
25. The method of making a hair care article according to claim 22 , wherein the surface resident coating comprising the inorganic particulate perfume complex is applied to the porous dissolvable solid substrate having a moisture content of about 5% to about 20%.
26. The method of making a hair care article according to claim 22 , wherein the surface resident coating comprising the inorganic particulate perfume complex is applied to the porous dissolvable solid substrate having a moisture content of about 7% to about 15%.