Apparatus and methods for preparation of high-purity silicon rods using mixed core means
Disclosed are a method and an apparatus for preparing a polycrystalline silicon rod using a mixed core means, comprising: installing a first core means made of a resistive material together with a second core means made of silicon material in an inner space of a deposition reactor; electrically heating the first core means and pre-heating the second core by the first core means which is electrically heated; electrically heating the preheated second core means; and supplying a reaction gas into the inner space in a state where the first core means and the second core means are electrically heated for silicon deposition.
1. A method for preparing a polycrystalline silicon rod using a mixed core means, comprising:
(a) installing a first core means made of a resistive material together with a second core means made of a silicon material in an inner space of a deposition reactor;
(b) electrically heating the first core means for the purpose of heating the first core means without being cooled;
(c) pre-heating the second core means by radiation heat transfer by the first core means which is electrically heated;
(d) electrically heating the second core means after the second core means is pre-heated; and
(e) supplying a reaction gas into the inner space in a state where the first core means and the second core means are electrically heated for silicon deposition by thermal decomposition so that silicon deposition occurs outwardly on the first core means and on the second core means with a first deposition output and a second deposition output being formed on the first core means and on the second core means, respectively, at a reaction pressure in the range of 1-20 bar absolute and a reaction temperature in the range of 650-1300° C. based on the surface temperature of the first deposition output and/or the second deposition output.
2. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein, in the step of electrically heating the preheated second core means, the entire second core means is electrically heated simultaneously or the second core means is divided into a plurality of second core groups which start to be electrically heated in groups at different starting times.
3. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein, in the step of pre-heating the second core means, the second core means is pre-heated to a temperature in the range of 350-1,000° C. with the first core means being electrically heated to a temperature in the range of 400-3,000° C.
4. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein, in the step of pre-heating the second core means, the second core means is preheated in the inner space at a pressure in the range of 1-20 bar absolute under an atmosphere selected from the group consisting of hydrogen, nitrogen, argon, helium and a mixture thereof.
5. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein the reaction gas contains at least one silicon-containing component selected from the group consisting of monosilane (SiH 4 ), dichlorosilane (SiH 2 Cl 2 ), trichlorosilane (SiHCl 3 ), silicon tetrachloride (SiCl 4 ) and a mixture thereof.
6. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 5 , wherein the reaction gas further contains at least one gas component selected from the group consisting of hydrogen, nitrogen, argon, helium, hydrogen chloride, and a mixture thereof.
7. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein the silicon deposition occurs in the inner space at a reaction pressure in the range of 1-20 bar absolute and a reaction temperature in the range of 650-1,300° C. based on the surface temperature of the first deposition output and/or the second deposition output.
8. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein a solar-grade polycrystalline silicon to be used for solar cells is formed in the first deposition output, and an electronic-grade polycrystalline silicon to be used for semiconductor devices is formed in the second deposition output.
9. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein the resistive material is a metal or an alloy comprising at least one metal element selected from the group consisting of tungsten (W), rhenium (Re), osmium (Os), tantalum (Ta), molybdenum (Mo), niobium (Nb), iridium (Ir), ruthenium (Ru), technetium (Tc), hafnium (Hf), rhodium (Rh), vanadium (V), chromium (Cr), zirconium (Zr), platinum (Pt), thorium (Th), lanthanum (La), titanium (Ti), lutetium (Lu), yttrium (Y), ferrum (Fe), nickel (Ni), aluminum (Al) and a mixture thereof.
10. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein the resistive material is a ceramic metal material containing at least one component selected from the group consisting of molybdenum silicide (Mo—Si), lanthanum chromium oxide (La—Cr—O), zirconia and a mixture thereof.
11. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein the resistive material is a carbon-based material comprising at least one component selected from the group consisting of amorphous carbon, graphite, silicon carbide (SiC) and a mixture thereof.
12. The method for preparing the polycrystalline silicon rod using a mixed core means as set forth in claim 1 , wherein the silicon material is selected from the group consisting of intrinsic polycrystalline silicon, intrinsic single crystalline silicon, doped silicon and a mixture thereof.