Inorganic structure for molecular separations
A process of producing a structure for molecular separations includes providing a plurality of biopolymers. The biopolymers are selected from DNAs, RNAs, nucleic acid loops, nucleic acid hairpins, nucleic acid dumbbells, alkylated phosphonates, non-standard nucleobases, or combinations thereof. A sieve material, suitable for producing a structure for molecular separations, is provided around the biopolymers. The biopolymers are positioned in an arrangement for leaving pores suitable for molecular separations. The biopolymers are removed to leave pores in the sieve material and produce the structure suitable for molecular separations.
1. A process of producing a structure for molecular separations comprising:
providing a plurality of DNA molecules;
providing a material suitable for producing a structure having opposing major surfaces when the material is positioned around the DNA molecules;
positioning the DNA molecules in an arrangement for leaving pathways formed by the DNA molecules that extend substantially transversely from one major surface of the structure to an opposing major surface of the structure; and
removing the DNA molecules to leave the pathways formed by the DNA molecules that are substantially uniform in width along their length in the material, and through which pathways molecular separations occur.
2. The process of claim 1 wherein the DNA molecules are positioned before providing the material around the DNA molecules.
3. The process of claim 1 wherein the DNA molecules are positioned after providing the material around the DNA molecules.
4. The process of claim 1 wherein the material is formed into a membrane and the DNA molecules are positioned substantially perpendicularly to a major surface of the membrane.
5. The process of claim 4 wherein the DNA molecules are attached to a substrate surface and the material is applied onto the substrate surface and around the DNA molecules to form the membrane.
6. The process of claim 1 wherein the material produces a ceramic structure.
7. The process of claim 1 comprising an additional step, after removing the DNA molecules to leave the pathways, of reducing a diameter of the pathways in a controlled fashion.
8. The process of claim 1 comprising the additional steps of attaching catalytic materials to the DNA molecules before providing the material around the DNA molecules, and leaving the catalytic materials attached to the pathways when the DNA molecules are removed.
9. The process of claim 1 wherein the DNA molecules are single molecules of DNA.
10. The process of claim 9 wherein the DNA molecules are molecules of double-stranded DNA.
11. The process of claim 1 which further comprises controlling the length of the DNA molecules to control the length of the pathways.
12. The process of claim 1 which produces pathways in the material having a diameter between 5 angstroms and 19 angstroms.
13. The process of claim 1 wherein the DNA molecules are provided in a liquid crystalline state.
14. The process of claim 13 wherein the DNA molecules are single molecules of DNA.