Carbon nanotube slurry and field emission device
A carbon nanotube slurry consists of carbon nanotubes, glass powder, and organic carrier. The field emission device includes an insulative substrate, a cathode conductive layer, and an electron emission layer. The cathode conductive layer is located on a surface of the insulative substrate. The electron emission layer is located on a surface of the cathode conductive layer. The electron emission layer consists of a glass layer and a plurality of carbon nanotubes electrically connected to the cathode conductive layer.
1. A carbon nanotube slurry consisting of carbon nanotubes, glass powder, and organic carrier, wherein a weight percentage of the carbon nanotubes ranges from about 2% to about 5%, a weight percentage of the glass powder ranges from about 2% to about 5%, a weight percentage of the organic carrier ranges from about 90% to about 96%, and a viscosity of the carbon nanotube slurry ranges from about 13 Pa·s to about 16 Pa·s at a shear rate of about 10 second −1 .
2. The carbon nanotube slurry of claim 1 , wherein the weight percentage of the carbon nanotubes ranges from about 2.5% to about 3%, the weight percentage of the glass powder ranges from about 2.5% to about 3%, and the weight percentage of the organic carrier ranges from about 94% to about 95%.
3. The carbon nanotube slurry of claim 1 , wherein the carbon nanotubes are selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, and combinations thereof.
4. The carbon nanotube slurry of claim 1 , wherein a diameter of each of the carbon nanotubes ranges from about 0.5 nanometers to about 50 nanometers, and a length of each of the carbon nanotubes is larger than 1 micrometer.
5. The carbon nanotube slurry of claim 4 , wherein the diameter of each of the carbon nanotubes is less than or equal to 10 nanometers, and a length of each of the carbon nanotubes ranges from about 5 micrometers to about 15 micrometers.
6. The carbon nanotube slurry of claim 1 , wherein the glass powder is a low melting point glass powder with a melting point in a range from about 350° C. to about 600° C.
7. The carbon nanotube slurry of claim 1 , wherein an effective diameter of the glass powder is less than or equal to 10 micrometers.
8. The carbon nanotube slurry of claim 7 , wherein the effective diameter of the glass powder is less than or equal to 1 micrometer.
9. The carbon nanotube slurry of claim 1 , wherein the organic carrier is a volatilizable organic material and comprises a diluent, stabilizer, and plasticizer.
10. The carbon nanotube slurry of claim 1 , wherein the organic carrier comprises terpineol, ethyl cellulose, and dibutyl phthalate.
11. The carbon nanotube slurry of claim 1 , wherein the organic carrier comprises terpineol, ethyl cellulose, and dibutyl sebacate.
12. The carbon nanotube slurry of claim 11 , wherein the organic carrier further comprises a surfactant; a weight ratio of the terpineol, ethyl cellulose, dibutyl sebacate and surfactant is about 180:11:10:2.
13. The carbon nanotube slurry of claim 12 , wherein the surfactant is Span 40 with a formula of C 6 H 8 O(OH) 3 OCO(CH 2 ) 14 CH 3 C 22 H 42 O 6 .
14. The carbon nanotube slurry of claim 12 , wherein the surfactant is Span 60 with a formula of C 6 H 8 O(OH) 3 OCO(CH 2 ) 16 CH 3 C 24 H 46 O 6 .
15. A field emission device, comprising:
an insulative substrate;
a cathode conductive layer positioned on a surface of the insulative substrate; and
an electron emission layer located on a surface of the cathode conductive layer, and a layer consisting of low melting point glass and a plurality of carbon nanotubes electrically connected to the cathode conductive layer.
16. The field emission device of claim 15 , wherein the plurality of carbon nanotubes is fixed on the cathode conductive layer by the glass layer.
17. The field emission device of claim 15 , wherein a plurality of ends of the plurality of carbon nanotubes is exposed from the glass layer.
18. A carbon nanotube slurry being a mixture comprising a plurality of carbon nanotubes, a plurality of glass powders, and an organic carrier, wherein the organic carrier comprises a diluent, a stabilizer, and a plasticizer being selected from the group consisting of dibutyl phthalate and dibutyl sebacate.
19. The carbon nanotube slurry of claim 18 , wherein the diluent is terpineol, the stabilizer is ethyl cellulose, and the plasticizer is dibutyl sebacate.
20. The carbon nanotube slurry of claim 19 , wherein a weight ratio of the terpineol, ethyl cellulose, and dibutyl sebacate is about 180:11:10.