IP Library › Granted Patent US 8,441,010
Granted Patent B2
US 8,441,010 · App. 13/164,806 · Granted May 14, 2013

Semiconductor device

Inventors: Mitsuhiro Ichijo (Zama, JP); Toshiya Endo (Isehara, JP); Kunihiko Suzuki (Isehara, JP); Yasuhiko Takemura (Isehara, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
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Quick Facts
Patent No.
US 8,441,010
App. No.
13/164,806
Granted
May 14, 2013
Kind
B2
Abstract

In a transistor including an oxide semiconductor, hydrogen in the oxide semiconductor leads to degradation of electric characteristics of the transistor. Thus, an object is to provide a semiconductor device having good electrical characteristics. An insulating layer in contact with an oxide semiconductor layer where a channel region is formed is formed by a plasma CVD method using a silicon halide. The insulating layer thus formed has a hydrogen concentration less than 6×10 20 atoms/cm 3 and a halogen concentration greater than or equal to 1×10 20 atoms/cm 3 ; accordingly, hydrogen diffusion into the oxide semiconductor layer can be prevented and hydrogen in the oxide semiconductor layer is inactivated or released from the oxide semiconductor layer by the halogen, whereby a semiconductor device having good electrical characteristics can be provided.

Claims (37)

1. A semiconductor device comprising:

an insulating layer;

an oxide semiconductor layer on the insulating layer;

a gate insulating layer over the oxide semiconductor layer, a part of the gate insulating layer is in contact with the oxide semiconductor layer; and

a gate electrode layer over the gate insulating layer,

wherein a hydrogen concentration in the insulating layer is less than 6×10 20 atoms/cm 3 and a halogen concentration in the insulating layer is greater than or equal to 1×10 20 atoms/cm 3 .

2. The semiconductor device according to claim 1 , wherein the insulating layer is an oxide insulating layer.

3. The semiconductor device according to claim 1 , wherein the gate insulating layer comprises silicon oxide, silicon oxynitride, silicon nitride oxide, hafnium oxide, aluminum oxide, or tantalum oxide.

4. The semiconductor device according to claim 1 , wherein a thickness of the insulating layer is five or more times as thick as a total thickness of the oxide semiconductor layer and the gate insulating layer.

5. The semiconductor device according to claim 1 , wherein the insulating layer is provided between a substrate and the oxide semiconductor layer.

6. The semiconductor device according to claim 1 , wherein the halogen is fluorine.

7. The semiconductor device according to claim 1 , wherein the insulating layer is formed by a plasma CVD method using a silicon halide.

8. A semiconductor device comprising:

an insulating layer;

an oxide semiconductor layer on the insulating layer;

a gate insulating layer over the oxide semiconductor layer, a part of the gate insulating layer is in contact with the oxide semiconductor layer; and

a gate electrode layer over the gate insulating layer,

wherein a hydrogen concentration in the insulating layer is less than 6×10 20 atoms/cm 3 and a halogen concentration in the insulating layer is greater than or equal to 1×10 20 atoms/cm 3 , and

wherein a hydrogen concentration in the gate insulating layer is less than 6×10 20 atoms/cm 3 and a halogen concentration in the gate insulating layer is greater than or equal to 1×10 20 atoms/cm 3 .

9. The semiconductor device according to claim 8 , wherein the insulating layer is an oxide insulating layer.

10. The semiconductor device according to claim 8 , wherein the gate insulating layer comprises silicon oxide, silicon oxynitride, silicon nitride oxide, hafnium oxide, aluminum oxide, or tantalum oxide.

11. The semiconductor device according to claim 8 , wherein a thickness of the insulating layer is five or more times as thick as a total thickness of the oxide semiconductor layer and the gate insulating layer.

12. The semiconductor device according to claim 8 , wherein the insulating layer is provided between a substrate and the oxide semiconductor layer.

13. The semiconductor device according to claim 8 , wherein the halogen is fluorine.

14. The semiconductor device according to claim 8 , wherein the insulating layer is formed by a plasma CVD method using a silicon halide.

15. A semiconductor device comprising:

an oxide semiconductor layer;

a gate electrode layer;

a gate insulating layer formed between the gate electrode layer and the oxide semiconductor layer; and

an insulating layer that faces the gate insulating layer with the oxide semiconductor layer interposed therebetween, the insulating layer being in contact with the oxide semiconductor layer,

wherein a hydrogen concentration in the insulating layer is less than 6×10 20 atoms/cm 3 and a halogen concentration in the insulating layer is greater than or equal to 1×10 20 atoms/cm 3 , and

wherein the insulating layer is formed by a plasma CVD method using a silicon halide.

16. The semiconductor device according to claim 15 , wherein the insulating layer is an oxide insulating layer.

17. The semiconductor device according to claim 15 , wherein the gate insulating layer comprises silicon oxide, silicon oxynitride, silicon nitride oxide, hafnium oxide, aluminum oxide, or tantalum oxide.

18. The semiconductor device according to claim 15 , wherein a thickness of the insulating layer is five or more times as thick as a total thickness of the oxide semiconductor layer and the gate insulating layer.

19. The semiconductor device according to claim 15 , wherein the insulating layer is provided between a substrate and the oxide semiconductor layer.

20. The semiconductor device according to claim 15 , wherein the halogen is fluorine.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 21, 2011
From: ICHIJO, MITSUHIRO; ENDO, TOSHIYA; SUZUKI, KUNIHIKO; TAKEMURA, YASUHIKO
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 026469/0003 →
Priority Claims (1)
JP 2010-150849 · Jul 1, 2010 · national
Continuity (1)
Related Publication 20120001168A1 · Jan 5, 2012