IP Library Granted Patent US 8,444,742
Granted Patent B2
US 8,444,742 · App. 13/278,444 · Granted May 21, 2013

Soluble calcium fertilizer formulation

Inventors: Andrew G Smith (Spring Grove, PA); Charles H Svec (Hanover, PA); Michael D Fiery (Hanover, PA)
Assignee: Miller Chemical & Fertilizer Corporation
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Quick Facts
Patent No.
US 8,444,742
App. No.
13/278,444
Granted
May 21, 2013
Kind
B2
Abstract

A concentrated aqueous fertilizer which is readily water-soluble and a method of applying the solubilized dilute fertilizer to crops to enhance crop production are described. The dry fertilizer contains a contains nitrogen, phosphorus and potassium compounds, as well as a mixture of plant growth stimulators including at least one of each of growth promoters, vitamins, amino acids, carbohydrates/polysaccharides, and adjuvants.

Claims (22)

1. A concentrated fertilizer for dilution and application in liquid form, said fertilizer consisting essentially of

water,

a dissolved calcium compound,

a dissolved boron compound,

proline, hydroxyproline, L-tryptophan, glycolic acid, and at least one further amino acid, about 3% by weight to about 8% by weight of a nitrogen compound,

at least one vitamin, and

at least one adjuvant compound in an amount of about 5% to 10% by weight of the formulation,

wherein the ratio of calcium to boron is about 10 parts calcium to 1 part boron, whereupon when diluted to final liquid form for application the fertilizer contains at least about 2% calcium and at least about 0.2% boron.

2. The fertilizer according to claim 1 , wherein the adjuvant is present in an amount from about 2% by weight to about 10% by weight of the total formulation.

3. The fertilizer according to claim 1 , wherein the L-tryptophan is present in an amount of about 0.025% to about 0.075% w/w of the total dry fertilizer.

4. The fertilizer according to claim 3 , wherein the L-tryptophan is present in an amount of about 0.05% w/w of the total dry fertilizer.

5. The fertilizer according to claim 1 , wherein the glycolic acid is present in an amount of about 0.03 to 0.06% w/w of the total fertilizer.

6. The fertilizer according to claim 5 , wherein the glycolic acid is present in an amount of about 0.04% w/w of the total fertilizer.

7. The fertilizer according to claim 1 , wherein the hydroxyproline is present in an amount of about 0.04 to 0.06% w/w of the total fertilizer.

8. The fertilizer according to claim 7 , wherein the hydroxyproline is present in an amount of about 0.05% w/w of the total fertilizer.

9. The fertilizer according to claim 1 , wherein the proline and hydroxyproline are present in a ratio of about 1 to about 1 by weight.

10. The fertilizer according to claim 1 , comprising about 3 to 7% of an adjuvant selected from the group consisting of non-alcohol phosphate esters.

11. The fertilizer according to claim 1 , wherein the calcium is in the form of calcium hypophosphite, calcium EDTA chelate, or a combination thereof.

12. The fertilizer according to claim 1 , wherein the at least one vitamin comprises about 2 to 4% w/w of a vitamin mix comprising ascorbic acid, biotin, d-Biotin, pyridoxine-HCl, thiamine hydrochloride, thiamine mononitrate, riboflavin, folic acid, niacin, niacinamide, pantothenic acid, pyridoxine hydrochloride and inert carriers.

13. The fertilizer according to claim 1 , wherein the at least one further amino acid comprises about 0.25 to 0.75% w/w of an amino acid blend comprising: acetaminophen, caffeine, anthranilic acid, L-arginine, Betaine hydrochloride, choline bitartrate, L-glutamic acid, L-alanine, L-cycstein or a salt or hydrate thereof, L-Lysine hydrochloride; mannitol, L-proline, salicylic acid, L-serine, sorbitol, succinic acid, calcium EDTA chelate, L-tryptophan, based on the total weight of the fertilizer concentrate.

14. The fertilizer according to claim 13 , wherein the amino acid blend further comprises an inert anti-caking agent.

15. A final liquid fertilizer formulation ready for application, said fertilizer formulation consisting of an aqueous solution consisting of water, inert components, at least about 2% calcium, at least about 0.2% boron, said calcium and boron being in a ratio of about 10 parts by weight calcium to 1 part by weight boron, proline, hydroxyproline, about 10 to about 1000 parts part million (ppm) L-tryptophan, and about 10 to about 1000 ppm glycolic acid.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Oct 8, 2019
From: PNC BANK, NATIONAL ASSOCIATION
To: MILLER CHEMICAL & FERTILIZER, LLC
Reel/Frame 050658/0832 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL/FRAME - : 033062-0888 Recorded Apr 8, 2019
From: WILMINGTON TRUST NATIONAL ASSOCATION
To: MILLER CHEMICAL & FERTILIZER, LLC
Reel/Frame 048825/0279 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 15, 2014
From: MILLER CHEMICAL & FERTILIZER CORPORATION
To: MILLER CHEMICAL & FERTILIZER, LLC
Reel/Frame 033953/0747 →
RELEASE OF SECURITY INTEREST Recorded Jun 12, 2014
From: PNC BANK NATIONAL ASSOCIATION, AS ADMINSTRATIVE AGENT
To: ALCO INDUSTRIES, INC.; MILLER CHEMICAL & FERTILIZER CORPORATION; MODERN EQUIPMENT COMPANY
Reel/Frame 033135/0230 →
SECURITY INTEREST Recorded Jun 2, 2014
From: MILLER CHEMICAL & FERTILIZER, LLC
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 033072/0825 →
SECURITY INTEREST Recorded May 30, 2014
From: MILLER CHEMICAL & FERTILIZER, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 033062/0888 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 8, 2011
From: SMITH, ANDREW G; SVEC, CHARLES H; FIERY, MICHAEL D
To: MILLER CHEMICAL & FERTILIZER CORPORATION
Reel/Frame 027191/0600 →
Continuity (2)
Provisional Application 61407092 · Oct 27, 2010
Related Publication 20120103041A1 · May 3, 2012