Organic semiconductor compositions with nanoparticles
A method of fabricating a circuit includes chemically bonding a coating to a plurality of nanoparticles. The nanoparticles are dispersed in a medium comprising organic molecules. An organic semiconductor channel is formed that comprises the medium. A plurality of electrodes is formed over the substrate. The electrodes are located to function as two of a gate electrode, a drain electrode, and a source electrode of a field-effect transistor.
1. A method of fabricating an electronic device, comprising:
forming an organic semiconductor channel on a substrate, the channel including:
a plurality of nanoparticles having a chemically bonded coating on an outer surface of the nanoparticles; and
the coated nanoparticles dispersed in a medium comprising organic molecules, wherein said medium includes a plurality of crystalline regions and amorphous regions between said crystalline regions, each crystalline region of said plurality of crystalline regions includes one of the coated nanoparticles, and wherein said medium and the coated nanoparticles dispersed therein form a semiconducting solid of the channel; and
forming a plurality of electrodes over the substrate, wherein a first electrode and a second electrodes of the plurality of electrodes that contact the organic semiconductor channel are configured as a drain electrode, and a source electrode, respectively and a source electrode, respectively.
2. The method of claim 1 , wherein the chemical bonding modifies a polarity of the nanoparticles.
3. The method of claim 1 , wherein the coating comprises a compatibility agent.
4. The method of claim 1 , wherein chemically bonding a coating comprises exposing the nanoparticles to a derivative of trimethoxy silane.
5. The method of claim 1 , wherein the organic molecules are semiconducting polymer chains.
6. The method of claim 5 , wherein a viscosity of a solution comprising the semiconducting polymer chains is increased by dispersion of the nanoparticles therein.
7. The method of claim 1 , wherein the nanoparticles comprise silicon atoms.
8. The method of claim 1 , wherein the coating comprises a derivative of bromophenyl trimethoxy silane.
9. The method of claim 1 , wherein the nanoparticles have an average diameter of about 15 nm or less.
10. The method of claim 1 , wherein the organic molecules comprise poly(9,9-dioctylfluorene-alt-bithiophene).
11. The method of claim 1 , wherein the organic molecules are monodisperse compounds incorporating aromatic or heteroaromatic units.
12. The method of claim 1 , wherein forming the plurality of electrodes further including forming a gate electrode over the organic semiconductor channel.
13. The method of claim 1 , wherein the organic semiconductor channel and plurality of electrodes are part of an organic field effect transistor of the electronic device.