Azo compounds for polypropylene degradation
The invention relates to a process and compositions suitable for reducing by heat the molecular weight of polypropylene, propylene copolymers or polypropylene blends. Azo compounds bearing different substituents are added to the polymers.
1. A process for reducing the molecular weight of polypropylene, propylene copolymers or polypropylene blends, wherein at least one azo compound of formula (II)
R 1 R 2 R 3 —C—N═N—C—R 1 ′R 2 ″R 3 ″′ (II)
is added to the polypropylene, propylene copolymers or polypropylene blend to be degraded and the mixture is heated to a temperature of between 160 and 340° C.,
wherein
two of R 1 , R 2 and R 3 together with the carbon atom form a C 5 -C 8 cycloalkyl and one of R 1 , R 2 and R 3 is hydrogen and
R 1 ′, R 2 ″ and R 3 ″′ are each C 1 -C 20 alkyl.
2. A process according to claim 1 , wherein
two of R 1 , R 2 and R 3 together with the carbon atom form cyclohexyl and one of R 1 , R 2 and R 3 is hydrogen and
R 1 ′, R 2 ″ and R 3 ″′ are each C 1 -C 20 alkyl.
3. A process according to claim 1 , wherein that at least one azo compound (II) is added to a blend of polypropylene with polyethylene selected from the group consisting of high density polyethylene (HDPE), high molecular weight high density polyethylene (HMW HDPE), ultra high molecular weight high density polyethylene (UHMW HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), branched low density polyethylene (BLDPE) and ethylene-propylene-diene terpolymers (EPDM) containing small proportions of diene.
4. A process according to claim 1 , where at least one azo compound is
5. A process according to claim 4 , wherein that at least one azo compound (II) is added to a blend of polypropylene with polyethylene selected from the group consisting of high density polyethylene (HDPE), high molecular weight high density polyethylene (HMW HDPE), ultra high molecular weight high density polyethylene (UHMW HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), branched low density polyethylene (BLDPE) and ethylene-propylene-diene terpolymers (EPDM) containing small proportions of diene.