Borate micro emulsion and method for making the same
The specification discloses a borate microemulsion product. In one embodiment, the borate microemulsion includes from about 24 to about 32 weight percent emulsified sodium pentaborate; and from about 24 to about 32 weight percent particulate boric acid suspended therein. The microemulsion has a density of about 9.5 to about 10.5 pounds per gallon at about room temperature. In certain embodiments, the microemulsion has a viscosity of about 1200 to about 1520 at a temperature of from about 66° F. to about 70° F. In certain other embodiments, microemulsion has a viscosity of about 1000 to about 3000 at a temperature of from about 70° F. to about 75° F.
1. A method for making a borate microemulsion, the method comprising the steps of:
mixing one part, by weight, acidic borate with from about 0.6 to about 1.4 parts, by weight, alkali borate and from about 1.5 to about 3 parts, by weight, water to form a first mixture;
reacting the first mixture at a temperature of from about 32° F. to about 212° F. to provide a first reaction product which comprises emulsified sodium pentaborate; and
mixing the first reaction product with an additional from about 0.5 to about 4 parts, by weight, acidic borate and from about 0.5 to about 2 parts, by weight, water to provide a second product which comprises emulsified sodium pentaborate and particulate boric acid suspended therein
wherein the acidic borate comprises a borate selected from the group consisting of orthoboric acid, metaboric acid, boric oxide, and mixtures thereof and
wherein the alkali borate comprises at least a sodium borate.
2. The method of claim 1 , wherein the alkali borate comprises a borate selected from the group consisting of tincal, kernite, anhydrous sodium tetraborate, sodium tetraborate pentahydrate, sodium tetraborate decahydrate, and mixtures thereof.
3. The method of claim 1 , wherein the alkali borate comprises at least ulexite.
4. The method of claim 1 , wherein the second product comprises from about 18 to about 38 weight percent emulsified sodium pentaborate and from about 18 to about 38 weight percent particulate boric acid.
5. The method of claim 1 , wherein the second product comprises about 10 weight percent elemental boron.
6. The method of claim 1 , wherein the second product has a viscosity of from about 1000 to about 3000 centipoise at a temperature of from about 70° F. to about 75° F.
7. The method of claim 1 , wherein the second product has a viscosity of from about 2000 to about 2800 centipoise at a temperature of from about 70° F. to about 75° F.
8. The method of claim 1 , wherein the second product has a density of from about 9 to about 11 pounds per gallon at about room temperature.
9. The method of claim 1 , wherein the second product has a pH of from about 6 to about 7.5.
10. The method of claim 1 , wherein the second product has a pH of from about 6.5 to about 7.
11. A method for making a borate microemulsion, the method comprising the steps of:
mixing one part, by weight, boric acid with from about 0.6 to about 1.4 parts, by weight, sodium tetraborate and from about 1.5 to about 3 parts, by weight, water to form a first mixture;
reacting the first mixture at a temperature of from about 40° F. to about 100° F. to provide a first reaction product which comprises emulsified sodium pentaborate; and
mixing the first reaction product with an additional from about 0.5 to about 4 parts, by weight, boric acid and from about 0.5 to about 2 parts, by weight, water to provide a second product which comprises emulsified sodium pentaborate and particulate boric acid suspended therein.
12. The method of claim 11 , wherein the sodium tetraborate comprises sodium tetraborate pentahydrate.
13. The method of claim 11 , wherein the boric acid comprises orthoboric acid.
14. The method of claim 11 , wherein the second product has a density of about 10.2 pounds per gallon at about room temperature.
15. The method of claim 11 , wherein the second product has a pH of from about 6.7 to about 6.9.
16. A method for making a borate microemulsion, the method comprising the steps of:
mixing one part, by weight, alkali borate with from about 1 to about 15 parts, by weight, acidic borate and from about 1 to about 20 parts, by weight, water to form a mixture; and
reacting the mixture at a temperature of from about 32° F. to about 212° F. to provide a reaction product which comprises emulsified sodium pentaborate and particulate boric acid suspended therein
wherein the acidic borate comprises a borate selected from the group consisting of orthoboric acid, metaboric acid, boric oxide, and mixtures thereof and
wherein the alkali borate comprises at least a sodium borate.
17. The method of claim 16 , wherein the alkali borate comprises a borate selected from the group consisting of tincal, kernite, anhydrous sodium tetraborate, sodium tetraborate pentahydrate, sodium tetraborate decahydrate, and mixtures thereof.
18. The method of claim 16 , wherein the alkali borate comprises at least ulexite.
19. The method of claim 16 , wherein the reaction product comprises from about 18 to about 38 weight percent emulsified sodium pentaborate and from about 18 to about 38 weight percent particulate boric acid.
20. The method of claim 16 , wherein the reaction product comprises about 10 weight percent elemental boron.
21. The method of claim 16 , wherein the reaction is carried out in a mixing vessel with a recirculation loop.
22. The method of claim 1 , wherein the alkali borate further comprises a borate selected from the group consisting of potassium borates, lithium borates, and mixtures thereof.
23. The method of claim 16 , wherein the alkali borate further comprises a borate selected from the group consisting of potassium borates, lithium borates, and mixtures thereof.