Solid solution lithium alloy cermet anodes
View Patent ↗A metal-ceramic composite (“cermet”) has been produced by a chemical reaction between a lithium compound and another metal. The cermet has advantageous physical properties, high surface area relative to lithium metal or its alloys, and is easily formed into a desired shape. An example is the formation of a lithium-magnesium nitride cermet by reaction of lithium nitride with magnesium. The reaction results in magnesium nitride grains coated with a layer of lithium. The nitride is inert when used in a battery. It supports the metal in a high surface area form, while stabilizing the electrode with respect to dendrite formation. By using an excess of magnesium metal in the reaction process, a cermet of magnesium nitride is produced, coated with a lithium-magnesium alloy of any desired composition. This alloy inhibits dendrite formation by causing lithium deposited on its surface to diffuse under a chemical potential into the bulk of the alloy.
1. A method for forming a lithium-metal composition, comprising:
providing Li 3 N powder;
mixing a metal (M) powder into the Li 3 N powder to form an alloy phase;
heating the alloy phase from 310° to 480° C. to cause a reaction that forms a free flowing powder comprising grains of a metal nitride coated with a Li-metal alloy or lithium, wherein the Li-metal alloy is a nitrogen free Li-metal alloy or the lithium is a nitrogen free lithium.
2. The method of claim 1 , wherein the Li-metal alloy is an intermetallic compound containing lithium.
3. The method of claim 1 , wherein the metal is selected from the group consisting of magnesium, aluminum, tin, silicon, antimony, germanium, gallium, indium, and their alloys with one another or with lithium.
4. A lithium metal composition produced by the method of claim 3 , wherein the metal nitride is silicon nitride and the lithium-metal composition is lithium-silicon.
5. The lithium metal composition produced by the method of claim 3 , wherein the metal nitride is aluminum nitride and the lithium-metal composition is lithium-aluminum.
6. The lithium metal composition produced by the method of claim 3 , wherein the metal nitride is magnesium nitride and the lithium-metal composition is lithium-magnesium.
7. The method of claim 1 , wherein the Li 3 N powder comprises a particle size of <150 μm and the metal (M) powder comprises a particle size of <45 μm.
8. The method of claim 1 , wherein the alloy phase is stable over a composition range between about 30% and 100% Li.
9. The method of claim 1 , wherein a second metal powder is mixed with the Li 3 N powder and the first metal powder prior to heating.
10. The method of claim 9 , wherein the first metal powder is magnesium and the second metal powder is tin.
11. The method of claim 9 , wherein the first metal powder is magnesium and the second metal powder is silicon.
12. An electrode suitable for use in a lithium ion battery comprising as the active material a nitrogen free lithium-metal composition formed by the reaction process of claim 1 .
13. The electrode of claim 12 , wherein the electrode is an anode.