Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom
Provided are thermoplastic elastomer compositions composed of a thermoplastic component, an elastomeric component, and at least one particulate composition. Particulate compositions are composed of a particulate material and a carrier medium. Exemplary particulate materials include minerals, mineral compounds, including mineral oxides, clays, carbon, nanotubes, and combinations thereof. Typical carrier mediums are one or more polar polymers, apolar polymers, one or more oils, poly α-olefins, or combinations thereof. The at least one particulate composition is dispersed within the thermoplastic component and/or the elastomeric component. Particulate compositions include clay grease compositions wherein a clay, e.g., an exfoliated clay, is utilized as a thickener.
1. A thermoplastic vulcanizate composition comprising:
a thermoplastic component,
an elastomeric component that is in the form of a fully-cured rubber dispersed in said thermoplastic component, wherein the rubber is an ethylene-propylene-diene copolymer and wherein the thermoplastic component includes polypropylene or a propylene-based copolymer, and
at least one particulate composition dispersed with said thermoplastic component, said elastomeric component, or both said thermoplastic and said elastomeric component; said particulate composition comprising:
a carrier medium, and
a particulate material having a thickness in one direction of less than about 50 angstroms and is dispersed in the carrier medium, wherein the particulate material is a clay selected from the group consisting of natural or synthetic phyllosilicate, smectic clay, montmorillonite, nontronite, beidellite, volkonskoite, laponite, hectorite, saponite, sauconite, magadite, kenyaite, stevensite, vermiculite, halloysite, aluminate oxides, hydrotalcite, and combinations thereof, and wherein the at least one particulate composition comprises from about 0.1 to about 65 weight percent clay, based upon the total weight of the particulate composition wherein the particulate composition is selected from the group consisting of lithium simple and complex soap greases, calcium simple and complex soap greases, sodium simple and complex greases, aluminum simple and complex greases, barium simple and complex greases and polyurea greases.
2. The thermoplastic elastomer composition of claim 1 , wherein the particulate composition is dispersed within the elastomeric component.
3. The thermoplastic elastomer composition of claim 1 , wherein the particulate material is an intercalated and exfoliated clay.
4. The thermoplastic elastomer composition of claim 1 , wherein the particulate material has a thickness in one direction of from about 3 to about 20 angstroms.
5. The thermoplastic elastomer composition of claim 1 , wherein the clay has a platelet thickness of less than about 50 angstroms.
6. The thermoplastic elastomer composition of claim 1 , wherein the particulate material is an intercalated and exfoliated clay.
7. The thermoplastic elastomer composition of claim 1 , wherein the at least one particulate composition comprises:
a first clay grease composition, and
a second clay grease composition,
wherein each of the first clay grease composition and the second clay grease composition are dispersed within the thermoplastic component, the elastomeric component, or both the thermoplastic component and the elastomeric component.
8. The thermoplastic elastomer composition of claim 7 , wherein the clay of each clay grease compositions has a platelet thickness of less than about 50 angstroms.
9. The thermoplastic elastomer composition of claim 7 , wherein the at least one particulate composition comprises from about 0.1 to about 65 weight percent clay, based upon the total weight of the particulate composition.
10. A method of preparing thermoplastic elastomer compositions comprising:
a. providing a thermoplastic component,
b. providing an elastomeric component that is in the form of at a fully-cured rubber dispersed in said thermoplastic component, wherein the rubber is an ethylene-propylene-diene copolymer and wherein the thermoplastic component includes polypropylene or a propylene-based copolymer, and
c. combining the thermoplastic component and elastomeric component with at least one particulate composition comprising:
a carrier medium, and
a particulate material having a thickness in one direction of less than about 50 angstroms and is dispersed in the carrier medium, wherein the particulate material is a clay selected from the group consisting of natural or synthetic phyllosilicate, smectic clay, montmorillonite, nontronite, beidellite, volkonskoite, laponite, hectorite, saponite, sauconite, magadite, kenyaite, stevensite, vermiculite, halloysite, aluminate oxides, hydrotalcite, and combinations thereof, and wherein the at least one particulate composition comprises from about 0.1 to about 65 weight percent clay, based upon the total weight of the particulate composition,
wherein the particulate composition is dispersed within the thermoplastic elastomer component, the elastomeric component, or both the thermoplastic component and the elastomeric component; and
wherein the particulate composition is selected from the group consisting of lithium simple and complex soap greases, calcium simple and complex soap greases, sodium simple and complex greases, aluminum simple and complex greases, barium simple and complex greases and polyurea greases.
11. The method of preparing a thermoplastic elastomer composition of claim 10 , further comprising the step of curing the elastomeric component.
12. The method of preparing a thermoplastic elastomer composition of claim 11 , wherein the curing step occurs prior to combining the thermoplastic component and elastomeric component with the particulate composition.
13. The method of preparing a thermoplastic elastomer composition of claim 11 , wherein the curing step dynamically vulcanizes the thermoplastic elastomer composition.
14. The method of preparing a thermoplastic elastomer composition of claim 10 , wherein the particulate material is a mineral, a mineral compound, a clay, carbon particles, nanotubes, or combination thereof.
15. The method of preparing a thermoplastic elastomer composition of claim 10 , wherein the at least one particulate composition comprises from about 0.1 to about 65 weight percent clay, based upon the total weight of the particulate composition.
16. The method of preparing a thermoplastic elastomer composition of claim 10 , wherein the particulate composition is a clay grease composition.
17. The method of preparing a thermoplastic elastomer composition of claim 10 , wherein the at least one particulate composition comprises:
a first clay grease composition, and
a second clay grease composition,
wherein each of the first clay grease composition and the second clay grease composition are independently dispersed within the thermoplastic component, the elastomeric component, or both the thermoplastic component and the elastomeric component.
18. The method of preparing a thermoplastic elastomer composition of claim 17 , wherein the first clay grease composition is combined with the thermoplastic component and elastomer component prior to a curing step and the second grease composition is combined with the thermoplastic component and elastomer component after the curing step.
19. An article prepared from the composition of claim 1 .
20. The composition of claim 1 , wherein the thermoplastic vulcanizate is characterized by a Shore A hardness in excess of 45.2.