Single step transesterification of biodiesel feedstock using a gaseous catalyst
Embodiments of the present application provide methods for processing biodiesel from feedstock using a single-step process. The methods can include, for example, use of a gaseous catalyst as part of the esterification/transesterification process. Embodiments of the present application also provide systems for the methods thereof.
1. A process for producing a fatty acyl methyl ester comprising:
providing reaction agents comprising a feedstock comprising triglycerides, methanol and gaseous HCl at a concentration of about 1M to about 3M;
contacting the reaction agents for a time of about 5 minutes to about 5 hours at a temperature of about 20° C. to about 60° C. to form a phase-separated reaction product comprising a first phase comprising methanol and HCl, and a second phase comprising a transesterified fatty acyl methyl ester;
recovering a component from the second phase, which component comprises the transesterified fatty acyl methyl ester; and
recovering methanol and HCl of said first phase by distilling said first phase at about 65° C. to 80° C.
2. A process for producing a fatty acyl alkyl ester comprising:
providing reaction agents comprising a feedstock comprising a fatty acid conjugate, an alcohol and a gaseous acid catalyst, and contacting said reaction agents under conditions comprising one or more of the following: a temperature of about 20° C. to about 60° C., a reaction time of about of 5 minutes to about 5 hours, and an acid concentration of at least 0.5M, wherein the contacting results in formation of a reaction product comprising a first component comprising a transesterified fatty acyl alkyl ester.
3. The process of claim 2 wherein said contacting occurs at a temperature of about 20° C. to about 60° C.
4. The process of claim 2 wherein said contacting occurs for a reaction time of about of 5 minutes to about 5 hours.
5. The process of claim 2 wherein said contacting comprises an acid having a concentration in said alcohol of at least 0.5M.
6. The process of claim 2 wherein said gaseous acid catalyst is at a concentration of from about 1.0 M to about 3.0M in said alcohol.
7. The process of claim 2 wherein said gaseous acid catalyst comprises one or more selected from the group consisting of acetyl chloride, BF 3 , HCl, HBr, HCN, HF, H 2 S and H 2 SO 4 .
8. The process of claim 2 wherein said acid is gaseous HCl.
9. The process of claim 2 wherein said alcohol comprises one or more selected from the group consisting of methanol, ethanol, propanol, butanol, pentanol, hexanol, heptanol, octanol, nonanol, decanol, benzyl alcohol, iso-butyl alcohol, n-butyl alcohol, 2-ethyl hexanol, furfuryl alcohol, iso-propyl alcohol, and n-propyl alcohol.
10. The process of claim 2 wherein said alcohol is methanol.
11. The process of claim 2 wherein said feedstock comprises algal bodies.
12. The process of claim 2 wherein said feedstock comprises unlysed algal bodies.
13. The process of claim 2 wherein said feedstock comprises at least one component selected from the group consisting of: an oil derived from a plant, an oil derived from an animal, a lipid, a fat, a grease, a cooking waste, a triglyceride, phospholipid, a glycolipid, or a neutral lipid.
14. The process of claim 2 wherein said fatty acid conjugate comprises at least one component selected from the group consisting of: a triglyceride, a phospholipid, a glycolipid, or a neutral lipid.
15. The process of claim 2 wherein said fatty acid conjugate comprises a triglyceride.
16. The process of claim 2 further comprising recovering said fatty acyl methyl ester, and said alcohol and said gaseous acid catalyst through phase separation.
17. The process of claim 13 further comprising distilling said alcohol and said gaseous acid catalyst wherein said distillation comprises a temperature of about 65° C. to 80° C. and wherein said distillation separates water from said alcohol and said gaseous acid catalyst.