Method and plant for treating crude gas, in particular biogas, containing methane and carbon dioxide in order to produce methane
A method for treating crude gas, in particular biogas, containing methane and carbon dioxide, in order to produce methane, and a plant suitable for carrying out the method. The method includes (a) washing the crude gas with an amine-containing washing solution, thereby forming a pure gas stream of methane and water, from which water is separated by subsequent cooling and condensation; (b) compressing and heating the washing solution containing CO 2 and sulfur compounds and expanding the washing solution in a first expansion stage, during a secondary reaction time of 280 to 1200 seconds and at a constant reaction temperature; (c) cooling the purified washing solution and expanding it in a second expansion stage to normal pressure, whereupon any residual amounts of soluble CO 2 and sulfur compounds are separated and the completely purified washing solution is cooled to normal temperature and returned to the washing stage.
1. A method of treating crude gases containing methane and carbon dioxide to produce methane, which comprises:
a) subjecting the crude gas to a single or multi-stage scrubbing process with an amine-containing scrubbing solution at an amine concentration of at least 15% with the formation of a pure gas stream consisting of methane and water, removing the water from the pure gas stream and, optionally, returning the water to a scrubbing circuit by downstream cooling and condensation;
b) compressing a scrubbing solution containing CO 2 and sulfur compounds obtained in step a) to a reaction pressure of at least 4 bar, heating to a temperature above 120° C. and expanding, in an initial expansion stage, to a pressure that is 1 to 3 bar below the reaction pressure, while maintaining a secondary reaction time of 280 to 1200 seconds and a constant reaction temperature, for removing a major proportion of the CO 2 and sulfur compounds from the scrubbing solution and drawing off as a gas stream;
c) cooling the thus purified scrubbing solution to a temperature below 50° C. and expanding in a second expansion stage to standard pressure, to remove residual amounts of soluble CO 2 and sulfur compounds still present to form a completely purified scrubbing solution, and cooling the completely purified scrubbing solution to standard temperature and returning to the scrubbing stage.
2. The method according to claim 1 , which comprises scrubbing the crude gas at standard pressure or at a slight vacuum up to 50 mbar, and with an amine-containing scrubbing solution at an amine concentration of at least 15% at standard temperature or temperatures up to 100° C.
3. The method according to claim 1 , wherein step b) comprises compressing the scrubbing solution to a reaction pressure of between 8 and 12 bar.
4. The method according to claim 1 , wherein the multi-stage scrubbing process includes an initial scrubbing stage in which more than 50% of a total amount of scrubbing solution required is used and wherein the scrubbing solutions of the individual scrubbing stages are combined and regeneratively processed.
5. The method according to claim 1 , which comprises heating the scrubbing solution obtained after washing to a required reaction temperature in two stages by way of indirectly heated heat exchangers.
6. The method according to claim 1 , which comprises conducting the gas stream containing CO 2 and sulfur compounds separated in an initial expansion stage through two heat exchangers connected in series and cooling to standard temperature and conveying to a downstream separator for removing water condensed from the gas stream and removing the water-free gas stream under controlled pressure.
7. The method according to claim 1 , which comprises using hot scrubbing solution removed from an initial expansion stage as a heat carrier for at least one of the heat exchangers and thereby cooling the scrubbing solution to a temperature of no more than 50° C.
8. The method according to claim 1 , which comprises heating the crude gas to a temperature of 20 to 60° C. in process step a) and adjusting to a pressure ranging from −20 to 150 mbar.
9. The method according to claim 1 , which comprises removing more than 95% of the proportions of CO 2 and sulfur compounds bound in the scrubbing solution during the initial expansion stage.
10. The method according to claim 1 , which comprises desulfurizing at least the gas stream removed from the initial expansion stage in a downstream desulphurization plant.
11. The method according to claim 1 , which comprises subjecting the scrubbing solution to an ultrasonic treatment during the initial expansion phase.