Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet
The present invention provides a water-dispersed acrylic PSA composition suitable for forming a PSA sheet. The PSA composition contains 100 parts by weight of an acrylic copolymer with a Tg of −70° C. to −50° C. obtained by polymerization of a monomer starting material containing 60 wt % or more of an alkyl (meth)acrylate with a C 8-12 alkyl group and 5 wt % or less of a radical polymerizable monomer with a carboxyl group. When an adhesive sheet is formed therefrom, it exhibits an average SUS adhesive strength of 11 N/20 mm or greater, PP adhesive strength of 8.5 N/20 mm or greater, 80° C. hold time of 1 hour or longer, and gap height of 10 mm or less in a curved surface adhesion test.
1. A water-dispersed pressure-sensitive adhesive composition comprising (a) as a base polymer thereof a water-dispersed acrylic copolymer (component L) with a glass transition temperature (Tg) in the range of −70° C. to −50° C., and (b) 10 to 40 parts by weight of a tackifying resin (component T) in relation to 100 parts by weight of the component L based on solid content,
wherein the component L is an acrylic copolymer obtained by polymerization of a monomer starting material comprising:
60 wt % or more of an alkyl (meth)acrylate having a C 8-12 alkyl group, and
5 wt % or less of a radical polymerizable monomer having a carboxyl group (monomer b), wherein the monomer b comprises acrylic acid and methacrylic acid at an acrylic acid/methacrylic acid weight ratio of 0.3 to 4; and
wherein, when a double-sided pressure-sensitive adhesive sheet is fabricated using the adhesive composition, the pressure-sensitive adhesive sheet satisfies all of the following properties:
(A) an average adhesive strength on stainless steel of 11 N/20 mm or greater on either side;
(B) an average adhesive strength on polypropylene of 8.5 N/20 mm or greater on either side;
(C) a hold time in an 80° C. holding strength test of 1 hour or longer on either side; and
(D) a gap height of an edge of a test piece in a curved surface adhesion test of 10 mm or less.
2. The composition according to claim 1 , wherein the polymer L constitutes an aqueous emulsion with an average particle size of 0.1 μm to 0.4 μm.
3. The composition according to claim 1 , wherein the monomer starting material comprising the monomer b in an amount of 1 to 3 wt %.
4. The composition according to claim 1 , wherein the monomer starting material further contains one or more types of a monomer (monomer c) selected from alkyl (meth)acrylates with a homopolymer Tg of −25° C. or higher (excluding a compound corresponding to monomer a) and cycloalkyl (meth)acrylates in an amount of 3 to 35 wt %.
5. The composition according to claim 4 , wherein the monomer c has a C 1-2 alkyl methacrylate as a main component thereof.
6. The composition according to claim 1 , wherein the monomer starting material further contains a monomer (monomer d) capable of forming a silanol group in an amount of 0.005 to 0.1 wt %.
7. A pressure-sensitive adhesive sheet, comprising a pressure-sensitive adhesive layer formed from the composition according to claim 1 .
8. The pressure-sensitive adhesive sheet according to claim 7 , wherein the pressure-sensitive adhesive layer is formed to have a gel fraction Gb of 30% to 60%.
9. The pressure-sensitive adhesive sheet according to claim 7 , constituted as a double-sided adhesive sheet comprising the adhesive layer on each side of a substrate sheet and satisfying all of the properties (A) through (D).
10. The double-sided adhesive sheet according to claim 9 , wherein the substrate is of a nonwoven fabric and the pressure-sensitive adhesive sheet has a tensile strength of 10 N/10 mm or greater measured both in a machine direction and a transverse direction of the nonwoven fabric.
11. The pressure-sensitive adhesive sheet according to claim 7 , wherein the pressure-sensitive adhesive sheet secures recyclable parts.
12. A double-sided pressure-sensitive adhesive sheet comprising a sheet-shaped substrate and the pressure-sensitive adhesive layer according to claim 7 formed on both sides of the sheet-shaped substrate, wherein a total amount of volatile organic compounds (TVOC) emitted from the sheet when the adhesive sheet is heated at 80° C. for 30 minutes is 1000 μg or less per gram of the adhesive sheet.
13. A water-dispersed pressure-sensitive adhesive composition comprising as a base polymer thereof a water-dispersed acrylic copolymer (component L) with a glass transition temperature (Tg) in the range of −70° C. to −50° C.,
wherein the component L is obtained by polymerization of a monomer starting material comprising 5 wt % or less of a radical polymerizable monomer having a carboxyl group (monomer b), wherein the monomer b comprises acrylic acid and methacrylic acid at an acrylic acid/methacrylic acid weight ratio of 0.3 to 4; and
wherein, when a double-sided adhesive sheet is fabricated using the adhesive composition, the pressure-sensitive adhesive sheet satisfies all of the following properties:
(B) an average adhesive strength on polypropylene of 8.5 N/20 mm or greater on either side;
(C) a hold time in an 80° C. holding strength test of 1 hour or longer on either side;
(D) a gap height at an edge of a test piece in a curved surface adhesion test of 10 mm or less; and
(H) a total amount of volatile organic compounds (TVOC) emitted from the sheet when heated for 30 min at 80° C. being 1000 μg or less per 1 gram of the adhesive sheet.
14. The composition according to claim 13 , wherein the base polymer consists of the component L.
15. The composition according to claim 1 , wherein the base polymer consists of the component L.