Refinery crude unit performance monitoring using advanced analytic techniques for raw material quality prediction
A method for the determination of optimal pipestill operation comprising the steps of: feeding a crude oil feedstream into the pipestill wherein the crude oil feedstream is separated into boiling range fractions, performing a virtual assay of the crude oil feedstream to determine predicted boiling range fraction yields, comparing the predicted boiling range fraction yields with the actual boiling range fraction yields from the pipestill to determine differences between these fraction yields, relating the difference between the fraction yields with the operation of the pipestill.
1. A method for the determination of optimal operation for a given crude oil feedstream of a refinery pipestill by determining a virtual assay of said crude oil feed comprising:
a) feeding a crude oil feedstream into said refinery pipestill wherein said crude oil feedstream is separated into boiling range fractions and determining the yields of the boiling range fractions.
b) performing a virtual assay of said crude oil feedstream by the steps in c, d and e,
c) determining an IR spectrum of said crude oil feedstream,
d) fitting said IR spectrum to a linear combination of known IR spectra in a database to determine the coefficients of the linear combination, wherein the database includes IR spectra of reference crude oils whose boiling range fraction yields are known,
e) determining the boiling point fractions yields of said crude oil feedstream from the coefficients of the linear combination and the boiling range fraction yields of the reference crudes,
f) comparing the predicted boiling range fraction yields with the actual boiling range fraction yields from the pipestill to determine differences between these fraction yields,
g) relating said difference between the fraction yields with the optimal operation of the refinery pipestill for the crude oil feedstream.
2. The method of claim 1 wherein said Virtual Assay is performed using a FT-IR spectrum and API gravity of the crude oil feedstream.
3. The method of claim 1 wherein said Virtual Assay is performed using a FT-IR spectrum, API gravity and viscosity of the crude oil feedstream.
4. The method of claim 1 wherein the virtual assay is performed on a sample of crude oil taken from an inlet line to the pipestill.
5. The method of claim 1 wherein the virtual assay is performed on a sample of crude oil taken from a well-mixed tank of crude oil that feeds an inlet line to the pipestill.
6. The method of claim 1 wherein the virtual assay is performed on an all-levels sample of crude oil taken from a nonhomogeneous tank of crude oil that feeds an inlet line to the pipestill.
7. The method of claim 1 wherein the virtual assay is performed on samples taken from more than one well-mixed tanks of crude oil that feed an inlet line to the pipestill.
8. The method of claim 1 further comprising the step of eliminating crude variability as the source of deviations in pipestill operation.