Method for manufacturing light control particles and light control film using light control particles obtained by the method
Disclosed is a method for manufacturing light control particles usable for a light control material comprising: a resin matrix made from a polymeric medium that is cured by irradiating with an energy beam; and a light control suspension comprising: a dispersing medium; and the light control particles that are dispersed in the dispersing medium so as to be in a flowing state, the method comprising the step of granulating after mixing elemental molecular iodine (A), an alkaline earth metal iodide (B), and a heterocyclic compound (C) with each other in a medium, wherein in the step of granulating, reaction is carried out in the presence of methanol in an amount of not less than 50 parts by mass but not more than 110 parts by mass relative to 100 parts by mass of the whole of components (A), (B) and (C). In this way, it is possible to provide a method for manufacturing light control particles wherein the effect of water is decreased in a granulating step of the method in order to yield effectively light control particles having a particle size and shape optimal for light control material and further a good reproducibility is attained.
1. A method for manufacturing light control particles usable for a light control material comprising:
a resin matrix made from a polymeric medium that is cured by irradiating with an energy beam; and
a light control suspension comprising: a dispersing medium; and the light control particles that are dispersed in the dispersing medium so as to be in a flowing state,
the method comprising the step of granulating after mixing elemental molecular iodine (A), an alkaline earth metal iodide (B), and a heterocyclic compound (C) with each other in a medium,
wherein in the step of granulating, reaction is carried out in the presence of methanol in an amount of not less than 50 parts by mass but not more than 110 parts by mass relative to 100 parts by mass of the whole of components (A), (B) and (C), and
wherein the heterocyclic compound (C) is a compound represented by the following Formula (1):
wherein R 1 and R 2 each independently represent hydrogen or an alkyl group, which is a saturated hydrocarbon, and the number of carbon atoms of the alkyl group ranges from 1 to 13, or a hydrate thereof.
2. The method for manufacturing light control particles according to claim 1 , wherein the alkaline earth metal iodide (B) is calcium iodide.
3. The method for manufacturing light control particles according to claim 1 , wherein the heterocyclic compound (C) is a compound represented by the following Formula (1):
wherein R 1 and R 2 each independently represent hydrogen or an alkyl group, which is a saturated hydrocarbon, and the number of carbon atoms of the alkyl group ranges from 1 to 13.
4. The method for manufacturing light control particles according to claim 1 , wherein in the step of granulating, cellulose nitrate is caused to coexist therewith.
5. A light control film, having a light control layer comprising a light control material comprising:
a resin matrix made from a polymeric medium that is cured by irradiating with an energy beam; and
a light control suspension comprising: a dispersing medium; and light control particles that are dispersed in the dispersing medium so as to be in a flowing state,
wherein the light control particles are obtained by the method for manufacturing light control particles according to claim 1 .
6. The method for manufacturing light control particles according to claim 1 , wherein R 1 and R 2 are independently selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl and t-butyl.
7. A light control film, having a light control layer comprising a light control material comprising:
a resin matrix made from a polymeric medium that is cured by irradiating with an energy beam; and
a light control suspension comprising: a dispersing medium; and light control particles that are dispersed in the dispersing medium so as to be in a flowing state,
wherein the light control particles are obtained by the method for manufacturing light control particles according to claim 6 .
8. The method for manufacturing light control particles according to claim 1 , wherein the heterocyclic compound (C) is pyrazine-2,5-dicarboxylic acid.
9. A light control film, having a light control layer comprising a light control material comprising:
a resin matrix made from a polymeric medium that is cured by irradiating with an energy beam; and
a light control suspension comprising: a dispersing medium; and light control particles that are dispersed in the dispersing medium so as to be in a flowing state,
wherein the light control particles are obtained by the method for manufacturing light control particles according to claim 8 .
10. The method for manufacturing light control particles according to claim 1 , wherein included with components (A), (B) and (C), is water, included in an amount of from 7.5 to 9.6 parts by mass relative to 100 parts by mass of the whole of components (A), (B) and (C).
11. The method for manufacturing light control particles according to claim 1 , wherein the amount of methanol present is 59.2 to 98.7 parts by mass relative to 100 parts by mass of the whole of components (A), (B) and (C).