Highly-branched starch, its production and uses
An object of the present invention is to provide a novel starchy substance having a retrogradation-resistance, a process for producing the starchy substance efficiently from a material starch by enzymatic reaction, and uses thereof. The present invention attains the above object by providing branched starch having 6-α-maltosyl- and/or 6-α-maltotetraosyl-structure(s) with a marked retrogradation-resistance, a process for producing the branched starch without lowering the molecular weight of material starch, and uses thereof.
1. A process for producing a modified branched starch, which comprises the steps of:
(a) allowing β-amylase to act on a branched starch, having a 6-α-maltosyl- and/or 6-α-maltotetraosyl-branched structures at the non-reducing ends of said branched starch, to hydrolyze said branched starch from its non-reducing ends by maltose unit to form a modified branched starch containing maltose; and
(b) collecting the formed modified branched starch.
2. The process of claim 1 , wherein the branched starch on which β-amylase is allowed to act forms 0.4% (w/w) or higher, on a dry solid basis, of 2,3,4-trimethyl-1,5,6-triacetyl-glucitol as a partially methylated compound when the branched starch is subjected to methylation analysis.