Electrochemical device comprising composite bipolar plate and method of using the same
An electrochemical device and methods of using the same. In one embodiment, the electrochemical device may be used as a fuel cell and/or as an electrolyzer and includes a membrane electrode assembly (MEA), an anodic gas diffusion medium in contact with the anode of the MEA, a cathodic gas diffusion medium in contact with the cathode, a first bipolar plate in contact with the anodic gas diffusion medium, and a second bipolar plate in contact with the cathodic gas diffusion medium. Each of the bipolar plates includes an electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane in contact with its respective gas diffusion medium, as well as a fluid chamber and a non-porous an electrically-conductive plate.
1. A fuel cell device comprising:
(a) a polymer electrolyte membrane, said polymer electrolyte membrane having opposing first and second faces;
(b) an anode electrically coupled to the first face of said polymer electrolyte membrane;
(c) a cathode electrically coupled to the second face of said polymer electrolyte membrane;
(d) an anodic gas diffusion medium defining an anode chamber in fluid communication with said anode;
(e) a cathodic gas diffusion medium defining a cathode chamber in fluid communication with said cathode; and
(f) a first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane in contact with said anodic gas diffusion medium, wherein the first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane comprises a solid polymer electrolyte and electrically-conductive metal particles selected from the group consisting of niobium particles and titanium particles, wherein the solid polymer electrolyte is a perfluorosulfonic acid (PFSA).
2. The fuel cell device as claimed in claim 1 wherein said first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane comprises the solid polymer electrolyte into which the electrically-conductive particles are dispersed.
3. The fuel cell device as claimed in claim 2 wherein the solid polymer electrolyte comprises a cation exchange ionomer membrane wherein the cation exchange group comprises —SO.sub.3.sup.−.
4. The fuel cell device as claimed in claim 1 further comprising a first fluid chamber in contact with said first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane opposite said anodic gas diffusion medium.
5. The fuel cell device as claimed in claim 4 further comprising a first electrically-conductive, non-porous sheet in contact with said first fluid chamber opposite said first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane.
6. The fuel cell device as claimed in claim 1 further comprising a second electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane, said second electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane being in contact with said cathodic gas diffusion medium.
7. The fuel cell device as claimed in claim 6 further comprising a second fluid chamber in contact with said second electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane opposite said cathodic gas diffusion medium.
8. The fuel cell device as claimed in claim 7 further comprising a second electrically-conductive, non-porous sheet in contact with said second fluid chamber opposite said second electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane.
9. The fuel cell device as claimed in claim 8 further comprising at least one of a vacuum coupled directly to said second fluid chamber and a liquid feed coupled directly to said first fluid chamber.
10. The fuel cell device as claimed in claim 8 further comprising a vacuum coupled directly to said second fluid chamber and a liquid feed coupled directly to said first fluid chamber.
11. A fuel cell stack comprising a plurality of the fuel cell devices of claim 1 arranged in a bipolar stack.
12. A fuel cell device comprising:
(a) a polymer electrolyte membrane, said polymer electrolyte membrane having opposing first and second faces;
(b) an anode electrically coupled to the first face of said polymer electrolyte membrane;
(c) a cathode electrically coupled to the second face of said polymer electrolyte membrane;
(d) an anodic gas diffusion medium defining an anode chamber in fluid communication with said anode;
(e) a cathodic gas diffusion medium defining a cathode chamber in fluid communication with said cathode; and
(f) a first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane in contact with said cathodic gas diffusion medium,
wherein the first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane comprises a solid polymer electrolyte and electrically-conductive metal particles selected from the group consisting of niobium particles and titanium particles, wherein the solid polymer electrolyte is a perfluorosulfonic acid (PFSA).
13. The fuel cell device as claimed in claim 12 wherein said first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane comprises the solid polymer electrolyte into which electrically-conductive particles are dispersed.
14. The fuel cell device as claimed in claim 13 wherein the solid polymer electrolyte comprises a cation exchange ionomer membrane wherein the cation exchange group comprises —SO.sub.3.sup.−.
15. The fuel cell device as claimed in claim 12 further comprising a first fluid chamber in contact with said first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane opposite said cathodic gas diffusion medium.
16. The fuel cell device as claimed in claim 15 further comprising a first electrically-conductive, non-porous sheet in contact with said first fluid chamber opposite said first electrically-conductive, chemically-inert, non-porous, liquid-permeable, substantially gas-impermeable membrane.
17. The fuel cell device as claimed in claim 16 further comprising a vacuum coupled directly to said first fluid chamber.
18. A fuel cell device stack comprising a plurality of the fuel cell devices of claim 12 arranged in a bipolar stack.