Thermo-shrinkable polyester film
Disclosed is a thermo-shrinkable polyester film having superior thermal shrinkage properties. The thermo-shrinkable polyester film has a strength of 3.5˜6.5 kg/mm 2 in a direction perpendicular to a main shrinking direction at an initial elongation less than 10%, an elongation at rupture of 50˜700% in a direction perpendicular to a main shrinking direction, a thickness uniformity (ΔR) of 4 or less and a shrinkage ratio of 5% or less in a direction perpendicular to a main shrinking direction, thus preventing the rupture thereof in a rolling process and so on and ensuring process stability and productivity.
1. A thermo-shrinkable polyester film, having:
a strength of 3.5˜6.5 kg/mm 2 in a direction perpendicular to a main shrinking direction at an initial elongation less than 10%;
an elongation at rupture of 50˜700% in the direction perpendicular to the main shrinking direction;
a thickness uniformity (ΔR) of 4 or less; and
a shrinkage ratio of 5% or less in the direction perpendicular to the main shrinking direction.
2. The thermo-shrinkable polyester film according to claim 1 , wherein a shrinkage ratio in the main shrinking direction in hot water at 95° C. is 40% or more, and an elongation at rupture in the main shrinking direction is 60˜120%.
3. The thermo-shrinkable polyester film according to claim 1 , wherein a melting peak temperature is 190˜210° C. and an intrinsic viscosity is 0.60˜0.72 dl/g.
4. The thermo-shrinkable polyester film according to claim 1 , wherein the thermo-shrinkable polyester film comprises at least one copolyester selected from among copolyesters prepared from a dicarboxylic acid component including one or more selected from among dicarboxylic acids including terephthalic acid, oxalic acid, malonic acid, succinic acid, adipic acid, suberic acid, azelaic acid, sebacic acid, phthalic acid, isophthalic acid, naphthalene dicarboxylic acid and diphenylether dicarboxylic acid, and from a diol component including one or more selected from among diols including ethyleneglycol, neopentylglycol, propyleneglycol, trimethyleneglycol, tetramethyleneglycol, hexamethyleneglycol, diethyleneglycol, polyalkyleneglycol and 1,4-cyclohexanedimethanol; or a mixture of homopolyester and copolyester.
5. The thermo-shrinkable polyester film according to claim 4 , wherein the copolyester comprises a dicarboxylic acid monomer including 80 mol % or more of a terephthalic acid monomer and a diol monomer including 60 mol % or more of an ethyleneglycol monomer.
6. The thermo-shrinkable polyester film according to claim 4 , wherein the copolyester has a glass transition temperature of 67˜77° C. and an intrinsic viscosity of 0.60˜0.75 dl/g.
7. The thermo-shrinkable polyester film according to claim 4 , wherein the homopolyester comprises polybutyleneterephthalate or polytriethylene terephthalate.
8. The thermo-shrinkable polyester film according to claim 7 , wherein the polybutyleneterephthalate is used in an amount of 7˜15 wt % based on a total amount of the polyester.