Heat-sensitive recording material
The present invention provides a heat-sensitive recording material that suffers no defective coating and is superior in color-exhibiting sensitivity, image quality, and chemical resistance. The heat-sensitive recording material successively comprising, on a support, an undercoat layer, a heat-sensitive recording layer containing a leuco dye and a developer, and a protective layer, wherein the heat-sensitive recording layer contains, as a main pigment, kaolin having an average particle diameter of 0.1 to 0.4 μm measured by a sedimentation method in an amount of 4 to 60 mass % based on a total solids content of the heat-sensitive recording layer, and wherein the heat-sensitive recording layer and the protective layer are formed by applying a heat-sensitive recording layer coating composition and a protective layer coating composition by a simultaneous multilayer curtain coating method, and drying resulting coatings.
1. A heat-sensitive recording material successively comprising, on a support, an undercoat layer, a heat-sensitive recording layer containing a leuco dye and a developer, and a protective layer,
wherein the heat-sensitive recording layer contains, as a main pigment, kaolin having an average particle diameter of 0.1 to 0.4 μm measured by a sedimentation method in an amount of 4 to 60 mass % based on a total solids content of the heat-sensitive recording layer,
and wherein the heat-sensitive recording layer and the protective layer are formed by applying a heat-sensitive recording layer coating composition and a protective layer coating composition by a simultaneous multilayer curtain coating method, and drying the resulting coatings.
2. The heat-sensitive recording material according to claim 1 , wherein the heat-sensitive recording layer coating composition comprises at least one cross-linked diphenylsulfone compound represented by a following general formula (I) in an amount of 0.3 to 10 mass % based on a total solids content of the heat-sensitive recording layer,
wherein n is an integer of 1 to 7.
3. The heat-sensitive recording material according to claim 2 , wherein the undercoat layer comprises magnesium carbonate in an amount of 0.1 to 5 mass % based on a total solids content of the undercoat layer.
4. The heat-sensitive recording material according to claim 2 , wherein the heat-sensitive recording material further comprises at least an ethylene-acrylic acid copolymer salt as an adhesive of the heat-sensitive recording layer.
5. The heat-sensitive recording material according to claim 4 , wherein the ethylene-acrylic acid copolymer salt is an ammonium salt or a sodium salt.
6. The heat-sensitive recording material according to claim 1 , wherein the undercoat layer comprises magnesium carbonate in an amount of 0.1 to 5 mass % based on a total solids content of the undercoat layer.
7. The heat-sensitive recording material according to claim 6 , wherein the heat-sensitive recording material further comprises at least an ethylene-acrylic acid copolymer salt as an adhesive of the heat-sensitive recording layer.
8. The heat-sensitive recording material according to claim 7 , wherein the ethylene-acrylic acid copolymer salt is an ammonium salt or a sodium salt.
9. The heat-sensitive recording material according to claim 6 , wherein the heat-sensitive recording material further comprises acetoacetyl-modified polyvinyl alcohol having a polymerization degree of 500 to 3000 as an adhesive of the heat-sensitive recording layer.
10. The heat-sensitive recording material according to claim 6 , wherein the heat-sensitive recording material further comprises a butadiene-based copolymer latex as an adhesive of the heat-sensitive recording layer.
11. The heat-sensitive recording material according to claim 6 , wherein the protective layer further comprises at least one polyvinyl alcohol selected from the group consist of acetoacetyl-modified polyvinyl alcohols and diacetone-modified polyvinyl alcohols.
12. The heat-sensitive recording material according to claim 1 , wherein the heat-sensitive recording material further comprises at least an ethylene-acrylic acid copolymer salt as an adhesive of the heat-sensitive recording layer.
13. The heat-sensitive recording material according to claim 12 , wherein the ethylene-acrylic acid copolymer salt is an ammonium salt or a sodium salt.
14. The heat-sensitive recording material according to claim 12 , wherein the heat-sensitive recording material further comprises acetoacetyl-modified polyvinyl alcohol having a polymerization degree of 500 to 3000 as an adhesive of the heat-sensitive recording layer.
15. The heat-sensitive recording material according to claim 12 , wherein the heat-sensitive recording material further comprises a butadiene-based copolymer latex as an adhesive of the heat-sensitive recording layer.
16. The heat-sensitive recording material according to claim 12 , wherein the protective layer further comprises at least one polyvinyl alcohol selected from the group consist of acetoacetyl-modified polyvinyl alcohols and diacetone-modified polyvinyl alcohols.
17. The heat-sensitive recording material according to claim 1 , wherein the heat-sensitive recording material further comprises acetoacetyl-modified polyvinyl alcohol having a polymerization degree of 500 to 3000 as an adhesive of the heat-sensitive recording layer.
18. The heat-sensitive recording material according to claim 1 , wherein the heat-sensitive recording material further comprises a butadiene-based copolymer latex as an adhesive of the heat-sensitive recording layer.
19. The heat-sensitive recording material according to claim 1 , wherein the protective layer further comprises at least one polyvinyl alcohol selected from the group consist of acetoacetyl-modified polyvinyl alcohols and diacetone-modified polyvinyl alcohols.