Steam activated non-lignocellulosic based carbons for ultracapacitors

1. A method for producing an activated carbon material comprising:

heating a non-lignocellulosic carbon precursor at a carbonization temperature effective to form a carbon material; and

reacting the carbon material with steam at an activation temperature effective to form an activated carbon material, wherein the reacting comprises incorporating the carbon material into one or more channels of a honeycomb substrate and flowing steam down the carbon-containing channels.

2. A method according to claim 1 , wherein the non-lignocellulosic carbon precursor is selected from the group consisting of wheat flour, walnut flour, corn flour, corn starch, corn meal, rice flour, potato flour, beets, millet, soybean, barley and cotton.

3. The method according to claim 1 , wherein the carbonization temperature ranges from about 600° C. to 800° C.

4. The method according to claim 1 , wherein the heating is performed in an inert atmosphere.

5. The method according to claim 1 , wherein the heating is performed in a nitrogen atmosphere.

6. The method according to claim 1 , wherein the activation temperature ranges from about 700° C. to 1000° C.

7. The method according to claim 1 , wherein the carbon material is reacted with steam for a period of time ranging from about 0.5 to 5 hours.

8. The method according to claim 1 , wherein the activated carbon material comprises:

pores having a size of ≦1 nm, which provide a combined pore volume of ≧0.3 cm 3 /g;

pores having a size of from >1 nm to ≦2 nm, which provide a combined pore volume of ≧0.05 cm 3 /g; and

<0.15 cm 3 /g combined pore volume of any pores having a size of >2 nm.

9. The method according to claim 1 , wherein the activated carbon material comprises:

pores having a size of ≦1 nm, which provide a combined pore volume of ≧0.2 cm 3 /g; and

pores having a size of from >1 nm to ≦2 nm, which provide a combined pore volume of ≧0.1 cm 3 /g.

10. The method according to claim 1 , further comprising washing the activated carbon material in an acidic solution.

11. The method according to claim 1 , further comprising heating the activated carbon material in an inert or reducing atmosphere.

12. The method according to claim 1 , further comprising grinding the carbon material prior to reacting the carbon material with steam.

13. A method for producing a carbon-based electrode comprising:

heating a non-lignocellulosic carbon precursor at a temperature effective to form a carbon material;

reacting the carbon material with steam to form an activated carbon material; and

forming a carbon-based electrode from the activated carbon material, wherein the reacting comprises incorporating the carbon material into one or more channels of a honeycomb substrate and flowing steam down the carbon-containing channels.

14. A method according to claim 13 , wherein the activated carbon material is dried to form a powder prior to forming the carbon-based electrode.

15. A method according to claim 13 , wherein the step of forming the carbon-based electrode comprises mixing the activated carbon material with at least one or carbon black and PTFE.

16. A method according to claim 13 , further comprising incorporating the carbon-based electrode into a energy storage device.

17. A method according to claim 16 , wherein the energy storage device is an ultracapacitor.

18. A method according to claim 17 , wherein the ultracapacitor has a design selected from the group consisting of a jelly roll design, a prismatic design, and a honeycomb design.