IP Library Granted Patent US 8,656,733
Granted Patent B2
US 8,656,733 · App. 13/778,772 · Granted Feb 25, 2014

Liquefaction method and system

Inventors: Mark Julian Roberts (Kempton, PA); Adam Adrian Brostow (Emmaus, PA)
Assignee: Air Products and Chemicals, Inc.
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Quick Facts
Patent No.
US 8,656,733
App. No.
13/778,772
Granted
Feb 25, 2014
Kind
B2
Abstract

Liquefaction using a closed loop refrigeration system, including compressing a gaseous refrigerant stream; cooling at least a portion of the compressed gaseous refrigerant stream in a first heat exchanger; expanding a first portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger to provide a first expanded gaseous refrigerant stream; cooling and substantially liquefying a feed gas stream to form a substantially liquefied feed gas stream in a second heat exchanger through indirect heat exchange against the first portion of the first expanded gaseous refrigerant stream; and further cooling a second portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger in a third heat exchanger by indirect heat exchange with a second portion of the first expanded gaseous refrigerant stream, wherein the first expanded gaseous refrigerant stream exiting the first expander is substantially vapor.

Claims (49)

1. A method of liquefaction using a closed loop refrigeration system, the method comprising the steps of:

(a) compressing a gaseous refrigerant stream in at least one compressor;

(b) cooling at least a portion of the compressed gaseous refrigerant stream in a first heat exchanger;

(c) expanding a first portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger in a first expander to provide a first expanded gaseous refrigerant stream;

(d) cooling and substantially liquefying a feed gas stream to form a substantially liquefied feed gas stream in a second heat exchanger through indirect heat exchange against the first portion of the first expanded gaseous refrigerant stream from the first expander; and

(e) further cooling a second portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger in a third heat exchanger by indirect heat exchange with a second portion of the first expanded gaseous refrigerant stream from the first expander,

wherein the first expanded gaseous refrigerant stream exiting the first expander is substantially vapor.

2. The method of claim 1 , further comprising subcooling the cooled and substantially liquefied feed gas stream through indirect heat exchange in a subcooler exchanger against a second expanded gaseous refrigerant stream exiting a second expander.

3. The method of claim 2 , wherein the second portion of the cooled, compressed gaseous refrigerant stream, after being further cooled in the third heat exchanger, is fed to the second expander to provide the second expanded gaseous refrigerant stream.

4. The method of claim 3 , wherein the second expanded gaseous refrigerant stream exiting the second expander is substantially vapor.

5. The method of claim 4 , wherein the second expanded gaseous refrigerant stream exiting the subcooler exchanger is compressed in a low pressure compressor; combined with the first portion of the first expanded gaseous refrigerant stream exiting the second heat exchanger and the second portion of the first expanded gaseous refrigerant stream exiting the third heat exchanger; and the mixed stream further compressed in a high pressure compressor.

6. The method of claim 1 , further comprising warming at least a portion of the first portion of the first expanded gaseous refrigerant stream exiting the second heat exchanger in the first heat exchanger.

7. The method of claim 1 , further comprising warming the second portion of the first expanded gaseous refrigerant stream exiting the third heat exchanger in the first heat exchanger.

8. The method of claim 1 , further comprising splitting the compressed gaseous refrigerant stream exiting the at least one compressor into a first portion and a second portion, cooling said first portion in a supplemental refrigeration system that comprises at least one stage of a vaporizing liquid refrigerant, cooling said second portion in the first heat exchanger in step (b) of claim 1 , and combining the cooled first portion with a portion of the cooled second portion for expansion in the first expander in step (c) of claim 1 .

9. The method of claim 1 , further comprising splitting the compressed gaseous refrigerant stream exiting the at least one compressor into a first portion and a second portion, expanding said first portion in a third expander, warming the resultant expanded first portion in the first heat exchanger, and cooling said second portion in the first heat exchanger in step (b) of claim 1 .

10. The method of claim 1 , wherein the feed gas stream for liquefaction is a natural gas stream.

11. The method of claim 1 , wherein the gaseous refrigerant stream is a nitrogen stream.

12. A closed loop system for liquefaction comprising:

a refrigeration circuit, the refrigeration circuit comprising:

a first compressor;

A first heat exchanger fluidly coupled to the first compressor and adapted to accept a gaseous refrigerant stream from the first compressor;

a first expander fluidly coupled to the first heat exchanger and adapted to accept a first stream of refrigerant from the first heat exchanger;

a second heat exchanger fluidly coupled to the first expander and adapted to accept a first expanded gaseous refrigerant stream from the first expander and a feed gas stream;

a third heat exchanger fluidly coupled to the first heat exchanger and to the first expander and adapted to accept a second stream of refrigerant from the first heat exchanger and a second expanded gaseous refrigerant stream from the first expander;

a second expander fluidly coupled to the third heat exchanger and adapted to accept a stream of refrigerant from the third heat exchanger; and

a subcooler exchanger fluidly coupled to the second heat exchanger and the second expander and adapted for acceptance of the feed gas stream from the second heat exchanger and an expanded gaseous refrigerant stream from the second expander,

wherein the first heat exchanger and the third heat exchanger may be combined into one heat exchanger, and

wherein the second heat exchanger and the subcooler exchanger may be combined into one heat exchanger.

13. A method of liquefaction using a closed loop refrigeration system, the method comprising the steps of:

(a) compressing a gaseous refrigerant stream in at least one compressor;

(b) cooling at least a portion of the compressed gaseous refrigerant stream in a first heat exchanger;

(c) removing from an intermediate section of the first heat exchanger a cooled, compressed gaseous refrigerant stream and expanding said portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger in a first expander to provide a first expanded gaseous refrigerant stream;

(d) cooling and substantially liquefying a feed gas stream to form a substantially liquefied feed gas stream in a second heat exchanger through indirect heat exchange against the first portion of the first expanded gaseous refrigerant stream from the first expander; and

(e) further cooling a second portion of the cooled, compressed gaseous refrigerant stream in the first heat exchanger by indirect heat exchange with a second portion of the first expanded gaseous refrigerant stream from the first expander,

wherein the first expanded gaseous refrigerant stream exiting the first expander is substantially vapor.

14. The method of claim 13 , further comprising subcooling the cooled and substantially liquefied feed gas stream through indirect heat exchange in the second exchanger against a second expanded gaseous refrigerant stream exiting a second expander.

15. The method of claim 14 , wherein the second portion of the cooled, compressed gaseous refrigerant stream, after being further cooled in the first heat exchanger, is fed to the second expander to provide the second expanded gaseous refrigerant stream.

16. The method of claim 15 , wherein the second expanded gaseous refrigerant stream exiting the second expander is substantially vapor.

17. The method of claim 13 , further comprising subcooling the cooled and substantially liquefied feed gas stream through indirect heat exchange in a subcooler exchanger against a second expanded gaseous refrigerant stream exiting a second expander.

18. The method of claim 13 , wherein the feed gas stream for liquefaction is a natural gas stream.

19. The method of claim 13 , wherein the gaseous refrigerant stream is a nitrogen stream.

20. A closed loop system for liquefaction, comprising:

a refrigeration circuit, the refrigeration circuit comprising:

a first compressor;

a first heat exchanger fluidly coupled to the first compressor and adapted to accept a compressed gaseous refrigerant stream from the first compressor;

a first expander fluidly coupled to the first heat exchanger and adapted to accept a first portion of the cooled, compressed gaseous refrigerant stream from an intermediate location of the first heat exchanger;

a second heat exchanger fluidly coupled to the first expander and adapted to accept a first expanded gaseous refrigerant stream from the first expander and a feed gas stream;

a second expander fluidly coupled to the first heat exchanger and adapted to accept a second portion of the cooled, compressed gaseous refrigerant stream from the first heat exchanger;

wherein the first heat exchanger is adapted to accept a second expanded gaseous refrigerant stream from the first expander, and wherein the second heat exchanger is adapted to receive an expanded gaseous refrigerant stream from the second expander.

Assignments (4)
CHANGE OF NAME Recorded Mar 25, 2026
From: HERCULES PROJECT COMPANY LLC
To: HONEYWELL LNG LLC
Reel/Frame 075228/0403 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 16, 2024
From: AIR PRODUCTS AND CHEMICALS, INC.
To: HERCULES PROJECT COMPANY LLC
Reel/Frame 068597/0136 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 6, 2013
From: ROBERTS, MARK JULIAN; BROSTOW, ADAM ADRIAN
To: AIR PRODUCTS AND CHEMICALS, INC.
Reel/Frame 030353/0372 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2013
From: ROBERTS, MARK JULIAN
To: AIR PRODUCTS AND CHEMICALS, INC.
Reel/Frame 030308/0027 →
Continuity (2)
Division 12272909 · Nov 18, 2008
Related Publication 20130174603A1 · Jul 11, 2013