Process of imparting wettability to a polyolefin fiber
Polyolefin woven and nonwoven fibers, filaments and fabrics made therefrom which comprise a melt blend which comprises (a) a polyolefin; and (b) at least one compound of the formula (I) R 1 -(hydrophilic oligomer) (I) wherein R 1 is a straight or branched chain alkyl of 22 to 40 carbon atoms and the hydrophilic oligomer is a homo- or co-oligomer consisting of monomer units derived from monomers selected from the group consisting of ethylene oxide, propylene oxide, ethylene glycol, propylene glycol, epichlorhydrin, acrylic acid, methacrylic acid, ethylene imine, caprolactone, vinyl alcohol and vinyl acetate; and wherein the hydrophilic oligomer consists of between 2 and 10 monomer units, exhibit excellent durable wettability. The fabrics are useful in disposable diapers, training pants, feminine napkins, tampons, incontinence care products, wet and dry wipes, wound dressings, surgical capes, filter medial, battery separators and the like.
1. A method for imparting permanent wettability to a polyolefin fiber, filament or woven or nonwoven fabric made therefrom, comprising melt extruding a mixture comprising (a) a thermoplastic polyolefin and (b) at least one compound of the formula (I) into a plurality of fibers and cooling the fibers, wherein formula (I) is
R 1 -(hydrophilic oligomer) (I)
wherein
R 1 is a straight or branched chain alkyl of 22 to 40 carbon atoms and the hydrophilic oligomer is a homo- or co-oligomer consisting of monomer units derived from monomers selected from the group consisting of ethylene oxide, propylene oxide, ethylene glycol, propylene glycol, epichlorhydrin, acrylic acid, methacrylic acid, ethylene imine, caprolactone, vinyl alcohol and vinyl acetate;
and wherein the hydrophilic oligomer consists of between 2 and 10 monomer units.
2. A method according to claim 1 wherein the polyolefin is polypropylene or polyethylene.
3. A method according to claim 1 wherein said fibers are drawn into a plurality of continuous filaments, a web is formed from said filaments and the filaments are at least partially bonded to form a fabric.
4. A method according to claim 1 in which the fibers or filaments are a bi-component fiber or filament comprising a polyolefin.
5. A method according to claim 1 in which component (b) is a compound of formula (Ia):
R 1 (OCH 2 CH 2 ) x OH (Ia)
where x is 2 to 10.
6. A method according to claim 5 wherein in the compound of formula (Ia), R 1 is a straight chain alkyl with an average value of 30 carbon atoms and x has an average value of 2.5, which compound is represented by formula (Ib):
CH 3 CH 2 (CH 2 CH 2 ) 13 CH 2 CH 2 (OCH 2 CH 2 ) 2 5 OH (Ib).
7. A method according to claim 1 in which the mixture comprises two different compounds of formula (I) which differ by having different average values for R 1 and/or different average values for the number of monomer units.
8. A method according to claim 6 in which the mixture comprises an additional compound of formula (I) which differs from the compound of formula (Ib) by having different average values for R 1 and/or different average values for the number of monomer units.
9. A method according to claim 1 wherein the compounds of component (b), in total, are present from about 0.1% to about 15% by weight, based on the weight of the polyolefin of component (a).
10. A method according to claim 9 wherein the compounds of component (b), in total, are present from about 1% to about 7% by weight, based on the weight of the polyolefin of component (a).
11. A method according to claim 1 wherein the mixture further comprises a stabilizer selected from the group consisting of hindered amine light stabilizers, phenolic antioxidants, phosphites or phosphonites, hydroxylamines, benzofuranones and hydroxyphenylbenzotriazole, hydroxybenzophenone or tris-aryl-s-triazine UV absorbers.
12. A method according to claim 1 in which component (b) is at least one ethoxylated aliphatic alcohol of the formula
CH 3 CH 2 (CH 2 CH 2 ) 13 CH 2 CH 2 (OCH 2 CH 2 ) x OH
where x has an average value of 2.5.