Base and radical generator, composition using same and method for curing same
The present invention relates to an aminimide compound having a structure represented by the following general formula (I) in the molecule thereof, relates to a curable composition using the aminimide compound and relates to a method for curing the composition; in which R 0 represents a hydrogen atom, an alkyl group which may have an optional substituent, an aryl group which may have an optional substituent, or a heterocyclic residue which may have an optional substituent. R 1 , R 2 and R 3 each independently represent a hydrogen atom, or an optional substituent. However, at least two of R 1 , R 2 and R 3 may bond to each other to form a cyclic structure.
1. An aminimide compound comprising, in the molecule thereof, a structure represented by the following general formula (I):
wherein R 0 represents a hydrogen atom, an alkyl group which may have a substituent, an aryl group which may have a substituent, or a heterocyclic residue which may have a substituent; R 1 , R 2 and R 3 each independently represent a hydrogen atom, or an optional substituent; provided that at least two of R 1 , R 2 and R 3 may bond to each other to form a cyclic structure.
2. The aminimide compound according to claim 1 , wherein R 0 in the general formula (I) is an aryl group which may have a substituent, or a heterocyclic residue which may have a substituent.
3. A composition comprising:
(A) an aminimide compound according to claim 1 ; and
(B) a compound to be polymerized by a radical and/or a base.
4. The composition according to claim 3 , wherein the (B) compound to be polymerized by a base is a compound having at least two epoxy groups in the molecule thereof.
5. The composition according to claim 3 , wherein the (B) compound to be polymerized by a base is a mixture of a compound having at least two epoxy groups in the molecule thereof and a compound having at least two thiol groups in the molecule thereof.
6. The composition according to claim 3 , wherein the (B) compound to be polymerized by a radical is a compound having at least one ethylenic unsaturated group in the molecule thereof.
7. The composition according to claim 3 , which contains the ingredient (A) in an amount of from 0.1 to 50 parts by weight relative to 100 parts by weight of the ingredient (B).
8. The composition according to claim 3 , further comprising (C) an active energy ray radical generator.
9. The composition according to claim 8 , which contains the ingredient (A) in an amount of from 0.1 to 50 parts by weight relative to 100 parts by weight of the ingredient (B), and contains the ingredient (C) in an amount of from 0.01 to 10 parts by weight relative to 1 part by weight of the ingredient (A).
10. A method for curing the composition according to claim 3 , the method comprising subjecting the composition to heating or irradiation with active energy rays, or to both heating and irradiation with active energy rays simultaneously, or to irradiation with active energy rays followed by heating.