Gas-phase phosgenation process
The present invention relates to a process for the phosgenation of amines in the gas phase, in which a specific type of heat exchanger is used for vaporizing the amines.
1. A process for producing an isocyanate comprising phosgenating an amine
in the gas phase in which at least one heat exchanger having
a. a heat transfer area per unit volume for the amine side of at least 1,000 m 2 /m 3 and
b. channels with a hydraulic diameter of from 1,000 to 10,000 μm for the flow of the amine
is used for liquid heating, vaporization and/or gas superheating of the amine.
2. The process of claim 1 in which the amine is flowed through a heat exchanger having an individual channel length of from 0.5 to 400 cm.
3. The process of claim 1 in which the amine is flowed through a heat exchanger comprising at least one stacked channel micro heat exchanger or milli channel tube heat exchanger type having channels with hydraulic diameters of from 2,000 to 5,000 μm and an individual channel length of from 10 to 400 cm.
4. The process of claim 1 in which a. is from 1×10 3 to 1×10 5 m 2 /m 3 .
5. The process of claim 1 in which the channels of the heat exchanger through which amine is flowed contain internals.
6. The process of claim 5 in which channels or space of the heat exchanger for conveying a heating medium contain internals.
7. The process of claim 1 in which channels or space of the heat exchanger for conveying a heating medium contain internals.
8. The process of claim 1 in which the amine's mean residence time in the heat exchanger for heating and/or vaporizing is in each case from 0.01 to 10 s.
9. The process of claim 8 in which the amine has a mean residence time in the heat exchanger for gas superheating of from 0.0005 to 1 s.
10. The process of claim 1 in which the amine's mean residence time in the heat exchanger for gas superheating is from 0.0005 to 1 s.
11. The process of claim 1 in which the amine is heated to a temperature of from 280 to 350° C. at an (absolute) pressure of from 800 to 1.600 mbar before entering the reactor.
12. Process according to any of claims 1 to 7 , characterized in that the phosgene is heated to a temperature of the phosgene stream of from 280 to 330° C. at an (absolute) pressure of from 700 to 1.500 mbar before entering the heat exchanger for phosgenation.
13. The process of claim 1 in which phosgene is used in a molar excess per amino group to be phosgenated of from 60 to 170%.
14. The process of claim 1 in which isophoronediamine (IPDA), hexamethylenediamine (HDA), bis(p-aminocyclohexyl)methane (PACM 20) or 1,8-diamino-4-(aminomethyl)octane (triaminononane) is the amine.