Carbon dioxide absorbent and method of using the same
In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.
1. An amino-siloxane composition comprising structure I
wherein R 1 is independently at each occurrence C 1 -C 5 alkyl; R 3 is independently at each occurrence R 1 or R 4 , wherein R 4 comprises structure II
and wherein R 2 is independently at each occurrence hydrogen or a C 1 -C 10 aliphatic radical; X is independently at each occurrence an NH 2 group or a cyano group; m is independently at each occurrence an integer from 1-5; n is independently at each occurrence an integer from 0-5; p is an integer from 0-100; and q is an integer from 0-500; with the proviso that at least one of R 3 is R 4 .
2. The composition according to claim 1 having structure Ia
3. The composition according to claim 1 having structure Ib
4. The composition according to claim 1 having structure Ic
5. The composition according to claim 1 having structure Ie
6. A reaction product of the composition of claim 1 with carbon dioxide.
7. An amino-siloxane composition comprising structure III
wherein R 1 is independently at each occurrence C 1 -C 5 alkyl; X is independently at each occurrence a NH 2 group or a cyano group; n is independently at each occurrence an integer from 0-5; and m is independently at each occurrence an integer from 1-5.
8. The composition according to claim 7 having structure IIIa
9. The composition according to claim 7 , having structure IIIb
10. A reaction product of the composition of claim 7 with carbon dioxide.
11. An amino-siloxane composition comprising structure I
wherein R 1 is independently at each occurrence C 1 -C 5 alkyl; and each R 3 independently comprises structure II
and wherein R 2 is independently at each occurrence hydrogen or a C 1 -C 10 aliphatic radical; X is independently at each occurrence an NH 2 group or a cyano group; m is independently at each occurrence an integer from 1-5; n is independently at each occurrence an integer from 0-5; p is an integer from 0-100; and q is an integer from 0-500.