IP Library Granted Patent US 8,747,978
Granted Patent B2
US 8,747,978 · App. 12/609,829 · Granted Jun 10, 2014

Multilayer flexible tubing

Inventors: Zhizhong Liu (Shrewsbury, MA); Charles Golub (Boxborough, MA); Heidi Sardinha (Millbury, MA); Wayne Edward Garver (Hudson, OH); Mark Colton (Rootstown, OH); Mark Simon (Pascoag, RI)
Assignee: Saint-Gobain Performance Plastics Corporation
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Quick Facts
Patent No.
US 8,747,978
App. No.
12/609,829
Granted
Jun 10, 2014
Kind
B2
Abstract

A flexible tube includes a first layer comprising a polyolefin material having a flexural modulus of not greater than 150 MPa and includes a second layer directly bonded to and in direct contact with the first layer. The second layer comprising a blend of propylenic polymer and styrenic block copolymer.

Claims (27)

1. A flexible tube comprising:

a first layer comprising a polyolefin material, wherein the first layer has a flexural modulus in a range of 10 MPa to 150 MPa; and

a second layer directly bonded to and in direct contact with the first layer, the second layer comprising a blend of propylenic polymer and styrenic block copolymer, wherein the propylenic polymer has a melt flow index (MFR) of 0.1 to 35 dg/min and wherein the styrenic block polymer is selected from the group consisting of a hydrogenated styrene-butadiene-styrene block copolymer, a hydrogenated styrene-isoprene-styrene block copolymer, a styrene-ethylene-butylene-styrene block copolymer (SEBS), a styrene-ethylene-propylene-styrene block copolymer (SEPS), a styrene-ethylene-ethylene-butylene-styrene block copolymer (SEEBS), a styrene-ethylene-ethylene-propylene-styrene block copolymer (SEEPS), and any combination thereof; the blend having a loss tangent value (tan δ) at 25° C. of at least 0.1.

2. The flexible tube of claim 1 , wherein the flexural modulus is not greater than 120 MPa.

3. The flexible tube of claim 1 , wherein the blend comprises 10 wt % to 80 wt % of the propylenic polymer.

4. The flexible tube of claim 1 , wherein the blend comprises 20 wt % to 90 wt % of the styrenic block copolymer.

5. The flexible tube of claim 1 , wherein the flexible tube exhibits a minimum bending radius of not greater than 1.0 inch.

6. The flexible tube of claim 1 , wherein the flexible tube exhibits a grip performance of at least 20 lb f at 25° C.

7. The flexible tube of claim 1 , wherein the first layer forms 5% to 20% of the thickness of the flexible tube.

8. The flexible tube of claim 1 , wherein the flexible tube has an average thickness of not greater than 250 mil.

9. The flexible tube of claim 1 , wherein the blend has a hardness in a range of 40 Shore A to 90 Shore A.

10. The flexible tube of claim 1 , wherein the blend has a storage modulus at 90° C. of at least 5 MPa.

11. The flexible tube of claim 1 , wherein the flexible tube has a Pump Life of at least 50 hours.

12. A flexible tube comprising:

a first layer comprising a polyolefin material, wherein the first layer has a flexural modulus in a range of 10 MPa to 150 MPa; and, the first layer forming an inner surface of the flexible tube, the inner surface defining a lumen; and

a second layer in direct contact with the first layer, the second layer comprising a blend of propylenic polymer and styrenic block copolymer, wherein the propylenic polymer has a melt flow index (MFR) of 0.1 to 35 dg/min and wherein the styrenic block polymer is selected from the group consisting of a hydrogenated styrene-butadiene-styrene block copolymer, a hydrogenated styrene-isoprene-styrene block copolymer, a styrene-ethylene-butylene-styrene block copolymer (SEBS), a styrene-ethylene-propylene-styrene block copolymer (SEPS), a styrene-ethylene-ethylene-butylene-styrene block copolymer (SEEBS), a styrene-ethylene-ethylene-propylene-styrene block copolymer (SEEPS), and any combination thereof, the blend having a loss tangent value (tan δ) at 25° C. of at least 0.1.

13. The flexible tube of claim 12 , wherein the loss tangent value is at least 0.30.

14. The flexible tube of claim 12 , wherein the flexural modulus is not greater than 120 MPa.

15. The flexible tube of claim 12 , wherein the second layer forms an outer surface of the flexible tube.

16. An apparatus comprising:

a fluid source; and

a flexible tube coupled to the fluid source at a first end, the flexible tube comprising:

a first layer comprising a polyolefin material, wherein the first layer has a flexural modulus in a range of 10 MPa to 150 MPa; and

a second layer directly bonded to and in direct contact with the first layer, the second layer comprising a blend of propylenic polymer and styrenic block copolymer, wherein the propylenic polymer has a melt flow index (MFR) of 0.1 to 35 dg/min and wherein the styrenic block polymer is selected from the group consisting of a hydrogenated styrene-butadiene-styrene block copolymer, a hydrogenated styrene-isoprene-styrene block copolymer, a styrene-ethylene-butylene-styrene block copolymer (SEBS), a styrene-ethylene-propylene-styrene block copolymer (SEPS), a styrene-ethylene-ethylene-butylene-styrene block copolymer (SEEBS), a styrene-ethylene-ethylene-propylene-styrene block copolymer (SEEPS), and any combination thereof; the blend having a loss tangent value (tan δ) at 25° C. of at least 0.1.

17. The apparatus of claim 16 , wherein a second end of the flexible tube is coupled to a valve.

18. The apparatus of claim 16 , wherein a second end of the flexible tube is coupled to a fitting.

19. The apparatus of claim 16 , wherein the flexible tube engages a pump.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2010
From: LIU, ZHIZHONG; GOLUB, CHARLES; SARDINHA, HEIDI; GARVER, WAYNE EDWARD; COLTON, MARK; SIMON, MARK
To: SAINT-GOBAIN PERFORMANCE PLASTICS CORPORATION
Reel/Frame 023894/0188 →
Continuity (2)
Provisional Application 61110336 · Oct 31, 2008
Related Publication 20100108172A1 · May 6, 2010