Compatibilized polypropylene and polylactic acid blends and methods of making and using same
A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.
1. A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier, wherein:
said polyolefin comprises polypropylene in an amount of from 51 wt. % to 99 wt. %;
said polylactic acid is present in an amount from 1 wt. % to 40 wt %, and
said reactive modifier comprises an epoxy functionalized polyolefin in an amount of from 0.5 wt. % to 15 wt. % based on the total weight of the composition, and wherein:
said epoxy functionalized polyolefin comprises glycidyl methacrylate grafted polypropylene and said epoxy functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %, and wherein the glycidyl methacrylate grafted polypropylene is prepared by grafting glycidyl methacrylate onto polypropylene in the presence of an initiator and a multi-functional acrylate comonomer, wherein the multi-functional acrylate comonomer comprises polyethylene glycol diacrylate or alkoxylated hexanediol diacrylate.
2. The composition of claim 1 wherein the polypropylene is a homopolymer comprising up to 5 wt. % of another C 2 -C 8 alpha olefin, a high crystallinity polypropylene homopolymer, a polypropylene heterophasic copolymer, or combinations thereof.
3. The composition of claim 1 wherein the polylactic acid comprises poly-L-lactide, poly-D-lactide, poly-LD-lactide, or combinations thereof.
4. The composition of claim 1 wherein the blend has a melt flow rate of from 0.5 g/10 min. to 100 g/10 min.
5. The composition of claim 1 , wherein the blend has a melt flow rate of from 1.5 g/10 min. to 50 g/10 min.
6. The composition of claim 1 , wherein the blend has a melt flow rate of from 5.0 g/10 min. to 20 g/10 min.
7. The composition of claim 1 , wherein the multi-functional acrylate comonomer comprises the polyethylene glycol diacrylate.
8. The composition of claim 1 , wherein the multi-functional acrylate comonomer comprises the alkoxylated hexanediol diacrylate.
9. The composition of claim 1 , wherein the glycidyl methacrylate is grafted onto the polypropylene in the presence of the initiator and the multi-functional acrylate comonomer within a reaction mixture comprising from 80 wt. % to 99.5 wt. % polypropylene.
10. The composition of claim 1 , wherein the polypropylene on which the glycidyl methacrylate is grafted on is a polypropylene homopolymer.
11. The composition of claim 1 , wherein the glycidyl methacrylate is grafted onto a backbone of the polypropylene.
12. The composition of claim 1 , wherein the glycidyl methacrylate and the multi-functional acrylate comonomer are both grafted onto a backbone of the polypropylene.