Antimicrobially effective use solutions comprising combinations of isothiazolones and amines
The invention relates to a microbicidal use solution which comprises a) one or more isothiazolin-3-ones and b) one or two organic amines selected from N-dodecylpropane-1,3-diamine and bis(aminopropyl)-dodecylamine and optionally c) one or more oxidizing agents. The use solution is preferably in the form of technical and domestic products.
1. A microbicidal use solution comprising:
a) one or more isothiazolin-3-ones (isothiazolones) selected from the group consisting of 2-methylisothiazolone (MIT), 1,2-n-octylisothiazolone (OIT), 1,2-benzisothiazolone (BIT), N-methylbenzisothiazolone, and n-butylbenzisothiazolone, and
b) one or two organic amines selected from N-dodecylpropane-1,3-diamine and bis(aminopropyl)-dodecylamine,
wherein the component a) is present in an amount of at most 1% by weight, based on the microbicidal use solution,
wherein microbicidal use solutions that comprise 1,2-benzisothiazolone (BIT) as the sole isothiazolone a) are excluded, and
wherein the microbicidal use solution comprises no chlorine-containing isothiazolones.
2. The microbicidal use solution according to claim 1 , wherein said microbicidal use solution comprises a mixture of MIT and BIT as component a), further isothiazolones being excluded.
3. The microbicidal use solution according to claim 1 , wherein said microbicidal use solution comprises a mixture of OIT and BIT as component a), further isothiazolones being excluded.
4. The microbicidal use solution according to claim 1 , wherein the amount of component a) is at most 0.8% by weight.
5. The microbicidal use solution according to claim 1 , wherein component b) is present in an amount of at least 0.0001% by weight, based on the microbicidal use solution.
6. The microbicidal use solution according to claim 1 , further comprising:
c) one or more oxidizing agents selected from the group consisting of chloric acid, perchloric acid, bromic acid, iodic acid, periodic acid and salts thereof, nitrates, H 2 O 2 , H 2 O 2 -donors, sodium perborate, urea peroxide, peroxides, percarboxylic acids and salts thereof, persulphuric acid and salts thereof, peroxodisulphonic acid and salts thereof, perphosphoric acids and salts thereof, transition metals, disulphides and oxidases.
7. The microbicidal use solution according to claim 6 , wherein component c) is present in an amount of at least 0.00001% by weight, based on the microbicidal use solution.
8. The microbicidal use solution according to claim 6 , further comprising at least one additional component selected from the group consisting of
d) water,
e) solvents and
f) further microbicidal active ingredients, functional additives or auxiliaries.
9. The microbicidal use solution according to claim 1 , wherein said microbicidal use solution has a pH in the range from 2 to 14.
10. The microbicidal use solution according to claim 5 , wherein the amount of component b) is at least 0.001% by weight.
11. The microbicidal use solution according to claim 6 , wherein the one or more oxidizing agents c) are selected from the group consisting of potassium iodate, sodium periodate, sodium bromate, H 2 O 2 and Cu(II) salts.
12. The microbicidal use solution according to claim 6 , wherein the microbicidal use solution comprises d) water and is free from e) solvents.
13. The microbicidal use solution according to claim 9 , wherein said microbicidal use solution has a pH of 4 to 12.
14. A method for the preservation of water-containing or water-dilutable technical or domestic products, comprising adding to said water-containing or water-dilutable technical or domestic products a combination of components a) and b) of the microbicidal use solution according to claim 1 , and optionally c) one or more oxidizing agents selected from the group consisting of chloric acid, perchloric acid, bromic acid, iodic acid, periodic acid and salts thereof, nitrates, H 2 O 2 , H 2 O 2 -donors, peroxides, percarboxylic acids and salts thereof, persulphuric acid and salts thereof, peroxodisulphonic acid and salts thereof, perphosphoric acids and salts thereof, transition metals, disulphides and oxidases.
15. The method according to claim 14 , the technical product is selected from the group consisting of polymer dispersions, paints, adhesives, paper coating slips, textile softening and sizing compositions, washing raw materials, cleaning and polishing compositions, spinning baths, cooling lubricants, leather treatment compositions and silicone and bitumen emulsions.