Solid oxide fuel cell and method for producing the same
An object of the present invention is to provide a fuel cell preventing formation of a diffusion layer containing Ca and other elements, and having an excellent power generation performance at low temperature by preventing breakdown of a crystal structure of an electrolyte by firing. Disclosed is a solid oxide fuel cell which includes a fuel electrode, a solid electrolyte, and an air electrode, each being sequentially laminated on the surface of a porous support. The porous support contains forsterite, and further has a calcium element (Ca) content of more than 0.2 mass % but not more than 2 mass % in terms of CaO.
1. A solid oxide fuel cell comprising a fuel electrode, a solid electrolyte, and an air electrode, each being sequentially laminated on a surface of a porous support, wherein
the porous support comprises forsterite, and further has a calcium element (Ca) content of more than 0.2 mass % but not more than 2 mass % in terms of CaO; and the porous support comprises a laminate including at least two layers.
2. The solid oxide fuel cell according to claim 1 , wherein the solid electrolyte comprises lanthanum-gallate-based oxide doped with Sr and Mg.
3. The solid oxide fuel cell according to claim 2 , wherein the solid electrolyte is represented by the general formula La 1-a Sr a Ga 1-b-c Mg b Co c O 3 , wherein 0.05≦a≦0.3, 0<b<0.3, and 0≦c≦0.15.
4. The solid oxide fuel cell according to claim 1 , wherein the porous support comprises a laminate including at least two layers, each having different Ca element contents.
5. A method for producing a solid oxide fuel cell comprising a fuel electrode, a solid electrolyte, and an air electrode, each being sequentially laminated on a surface of a porous support, the method comprising forming the porous support by firing a compact comprising forsterite and having a calcium element (Ca) content of more than 0.2 mass % but not more than 2 mass % in terms of CaO, wherein the compact comprises at least two layers, and sequentially forming the fuel electrode, the solid electrolyte, and the air electrode on the surface of the porous support.
6. The production method according to claim 5 , wherein the compact comprises at least two layers, each having different Ca contents, and at least one of the layers other than a layer at the fuel electrode side has a Ca content of more than 0.2 mass % but not more than 2 mass % in terms of CaO.
7. The solid oxide fuel cell according to claim 2 , wherein the porous support comprises a laminate including at least two layers, each having different Ca element contents.
8. The solid oxide fuel cell according to claim 3 , wherein the porous support comprises a laminate including at least two layers, each having different Ca element contents.
9. The solid oxide fuel cell according to claim 4 , wherein a Ca element content of the layer of the porous support at the fuel electrode side is less than that of the other layer(s) of the porous support.
10. The solid oxide fuel cell according to claim 9 wherein the solid electrolyte comprises lanthanum-gallate-based oxide doped with Sr and Mg.
11. The solid oxide fuel cell according to claim 10 , wherein the solid electrolyte is represented by the general formula La 1-a Sr a Ga 1-b-c Mg b Co c O 3 , wherein 0.05≦a≦0.3, 0<b<0.3, and 0≦c≦0.15.