Printing ink, apparatus and method
The present invention provides an inkjet ink comprising at least 30% by weight of organic solvent based on the total weight of the ink, a radiation curable material, a photoinitiator and optionally a colorant. The invention also provides an apparatus for printing the ink wherein the apparatus comprises at least one printhead, a means for evaporating solvent from the printed ink and a source of actinic radiation. Furthermore, the invention provides a method of inkjet printing comprising i) inkjet printing the inkjet ink as defined above on to a substrate; ii) evaporating at least a portion of the solvent from the printed ink; and iii) exposing the printed ink to actinic radiation to cure the radiation curable material.
1. An inkjet ink comprising at least 50% to 80% by weight of organic solvent based on the total weight of the ink, a radiation curable material, a photoinitiator and optionally a colourant, wherein the solvent is selected from glycol ethers, organic carbonates, lactones, dibasic esters, bio-solvents and mixtures thereof, wherein the radiation curable material is capable of polymerising by free radical polymerisation, and wherein the radiation curable material comprises 50 to 100% by weight of free radical curable monomer, based on the total weight of radiation curable material present in the ink.
2. The inkjet ink according to claim 1 wherein the organic solvent is present in an amount of 60% to 75% by weight based on the total weight of the ink.
3. The inkjet ink according to claim 1 wherein the solvent is selected from propylene carbonate and mixtures of propylene carbonate with one or more glycol ethers.
4. The inkjet ink according to claim 1 wherein the solvent is selected from mixtures of gamma butyrolactone with one or more glycol ethers and mixtures of gamma butyrolactone with one or more glycol ethers and propylene carbonate.
5. The inkjet ink according to claim 1 comprising less than 5% by weight of water based on the total weight of the ink.
6. The ink according to claim 1 wherein the radiation curable material is present in an amount of 2% to 45% by weight based on the total weight of the ink.
7. The inkjet ink according to claim 1 wherein the radiation curable material comprises a radiation curable oligomer.
8. The inkjet ink according to claim 7 wherein the radiation curable oligomer comprises a polyester, urethane, epoxy or polyether backbone.
9. The inkjet ink according to claim 1 wherein the radiation curable material comprises an oligomer having (meth)acrylate groups or a mixture of two or more oligomers having (meth)acrylate groups.
10. The inkjet ink according to claim 9 wherein the radiation curable material comprises a urethane acrylate oligomer.
11. The inkjet ink according to claim 1 which comprises less than 20% by weight of (meth)acrylates with a molecular weight of less than 450 based on the total weight of the ink.
12. The inkjet ink according to claim 1 which is substantially free of (meth)acrylates with a molecular weight of less than 450.
13. The inkjet ink according to claim 1 wherein the radiation curable material is capable of polymerising by cationic polymerisation.
14. The inkjet ink according to claim 13 wherein the radiation curable material is selected from oxetanes, cycloaliphatic epoxides, bisphenol A epoxides, epoxy novolacs and mixtures thereof.
15. The inkjet ink according to claim 1 wherein the radiation curable material comprises a combination of free radical polymerisable and cationically polymerisable materials.
16. An inkjet printing apparatus for printing a solvent-based radiation-curable inkjet ink onto a substrate comprising at least one printhead, a means for evaporating solvent from the printed ink and a source of actinic radiation, wherein the source of actinic radiation is positioned downstream from the means for evaporating solvent from the printed ink so that printed substrate is exposed to the means for evaporating solvent before it is exposed to radiation, allowing evaporation of the solvent before radiation curing of the ink.
17. An inkjet ink comprising at least 50% to 80% by weight of organic solvent based on the total weight of the ink, a radiation curable material, a photoinitiator and optionally a colourant, wherein the solvent is selected from glycol ethers, organic carbonates, lactones, dibasic esters, bio-solvents and mixtures thereof, wherein the radiation curable material comprises 50 to 100% by weight of free radical curable oligomer having a molecular weight of 600 to 4000 and 0 to 50% by weight of free radical curable monomer having a molecular weight of 450 or less based on the total weight of radiation curable material present in the ink; and wherein the photoinitiator is a free radical photoinitiator.
18. A method comprising:
i) inkjet printing the inkjet ink as defined in claim 1 or claim 17 on to a substrate;
ii) evaporating at least a portion of the solvent from the printed ink; and
iii) exposing the printed ink to actinic radiation to cure the radiation curable material.