IP Library Granted Patent US 8,806,967
Granted Patent B2
US 8,806,967 · App. 13/129,678 · Granted Aug 19, 2014

Immersible oxygen sensor for molten metals

Inventors: Ascencion Z. Villarreal, V (Neuvo Leon, MX); Paul A. Turner (Wauwatosa, WI); Richard A Falk (Pompano Beach, FL)
Assignee: Keystone Sensors, LLC
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Quick Facts
Patent No.
US 8,806,967
App. No.
13/129,678
Granted
Aug 19, 2014
Kind
B2
Abstract

An improved immersible oxygen probe for molten metals has a gas permeable body including an immersion end and a support end adapted for being supported by a lance. An oxygen cell and a thermocouple are supported in the immersion end of the body. An unobstructed gas flow passageway is provided through the gas permeable bodies and through the probe body from the immersion end to the support/connector end whereby gases released from the molten metal and sensor body during immersion readily pass through the probe and can escape from within the probe. Thus rapid analysis of the molten metal with improved accuracy within a few seconds after immersion is achieved.

Claims (32)

1. An immersible probe for molten metals comprising:

a first gas permeable body having an immersion end and a support end adapted for being supported by a lance;

at least one molten metal testing device supported by said body, the device including a test device adjacent to said immersion end for monitoring a characteristic of said metal;

an unobstructed gas flow passageway from said immersion end through said permeable body to said support end whereby gases released from a molten metal or contained in said permeable body during immersion of said immersion end can flow from within said probe into the atmosphere, the support end having connecting means for transmitting data from said testing device to remote electronic monitoring equipment; and

wherein the test device is exposed on the immersion end and is covered by an ungalvanized and uncoated steel cap having an irregular scalloped end surface that avoids formation of metal rings when melted during immersion of the probe.

2. A probe according to claim 1 wherein said gas permeable body is of an annular shape and is provided with a protruding shoulder adjacent to the immersion end thereof, the support end being adapted to fit within a supporting sleeve, said shoulder serving as a stop member for abutment by an end of said sleeve.

3. A probe according to claim 2 wherein said support end is also provided with a second gas permeable body of lesser diameter than said first body.

4. A probe according to claim 1 wherein said testing device comprises a stabilized zirconia oxygen cell and said probe also includes a thermocouple.

5. A probe according to claim 1 wherein said gas permeable body comprises a baked sand-resin material and said test device being baked in situ in said sand-resin material.

6. A probe according to claim 5 wherein said sand-resin material primarily comprises sand particles of 70-80 mesh size.

7. A probe according to claim 6 wherein said sand-resin material comprises approximately 5 weight % resin and approximately 5 weight % ferric oxide.

8. A probe according to claim 1 , wherein said test device comprises a stabilized zirconia oxygen cell and said probe also includes a platinum-rhodium thermocouple and a sampling mold all baked in situ in said first gas permeable body.

9. A probe according to claim 8 wherein electrical leads, welds and connectors for said test device and thermocouple cold junction components are baked in situ in said first gas permeable body.

10. A probe according to claim 1 wherein a support end thereof is provided with a connector having a plurality of passageways therethrough and wherein a fibrous filter material is lodged therein to screen out contaminants while permitting a flow of gases therethrough.

11. An immersible probe for molten metals comprising;

a gas permeable baked sand-resin body having an immersion end and a connection end adapted for being supported by a support pipe and containing a connector providing electrical

communication between said probe and monitoring apparatus;

molten metal testing devices supported in the immersion end of said body, the devices including a stabilized zirconia oxygen cell and a thermocouple, said sand-resin body and voids included therein allowing unobstructed gas flow through said immersion end, through said body and through said support end whereby gases released from a molten metal during immersion of said immersion end can enter and escape from within said probe;

wherein the molten metal testing devices are exposed on the immersion end and are covered by an ungalvanized and uncoated steel cap having an irregular scalloped end surface that avoids formation of metal rings when melted during immersion of the probe.

12. A probe according to claim 11 wherein sized sand-resin material primarily comprises sand particles of 70-90 mesh size.

13. A probe according to claim 11 wherein said gas permeable body is of an annular shape and is provided with a protruding shoulder adjacent to the immersion end thereof, the support end being adapted to fit within a first supporting sleeve, said shoulder serving as a stop member for abutment by an end of said first sleeve.

14. A probe according to claim 13 wherein a second supporting sleeve is adapted to fit within said first supporting sleeve and said body has a proximal end adapted to serve as a stop for a distal end of said second sleeve.

15. A probe according to claim 14 wherein said distal end of said second sleeve fits loosely within said first sleeve and is provided with a slot therethrough to allow escape of gases from within said probe.

16. A probe according to claim 15 wherein said first and second sleeves are stapled together.

17. A probe according to claim 15 wherein a second gas permeable sand-resin body, is spaced from said first gas permeable sand-resin body toward said connection end and a metal sampling mold is positioned between said first and second sand-resin bodies.

18. A probe according to claim 11 wherein a single point ground connection for said oxygen cell is provided by a metal conductor extending from said connector end toward said immersion end.

19. A probe according to claim 1 or 11 further comprising at least one combustible support tube, an end surface of said tube abutting and being adhered in a gas tight manner to a shoulder on the gas permeable body.

20. An immersible probe assembly for molten metals comprising:

a gas permeable baked sand-resin body having an immersion end and a connection end adapted for being supported by a support pipe and containing a communication connector providing electrical communication between said probe and monitoring apparatus, said communication connector having a plurality of openings retaining a heat resistant fibrous material adapted to filter impurities from gases flowing therethrough;

a molten metal testing device supported in the immersion end of said body, the device including a stabilized zirconia oxygen cell, said sand-resin body allowing unobstructed gas flow through said immersion end, through said body and through said support end whereby gases released from a molten metal during immersion of said immersion end can enter and escape from within said probe through said filter and through said openings;

a paperboard supporting tube adhered in gas tight fashion to a surface of said probe assembly; and

wherein the molten metal testing device is exposed on the immersion end and is covered by an ungalvanized and uncoated steel cap having an irregular scalloped end surface that avoids formation of metal rings when melted during immersion of the probe.

Assignments (8)
RELEASE OF SECURITY INTEREST Recorded Nov 3, 2015
From: EXPORT-IMPORT BANK OF INDIA
To: HENGYANG RAMON SCIENCE AND TECHNOLOGY INC. LTD.
Reel/Frame 037037/0894 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 16, 2015
From: KEYSTONE SENSORS, LLC
To: HENGYANG RAMON SCIENCE AND TECHNOLOGY INC. LTD.
Reel/Frame 036880/0076 →
RELEASE OF SECURITY INTEREST Recorded Oct 16, 2015
From: EXPORT-IMPORT BANK OF INDIA
To: KEYSTONE SENSORS, LLC
Reel/Frame 036880/0059 →
SECURITY INTEREST Recorded Jun 1, 2015
From: KEYSTONE SENSORS LLC
To: EXPORT-IMPORT BANK OF INDIA
Reel/Frame 035800/0383 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2014
From: BMO HARRIS BANK, N.A., SUCCESSOR BY MERGER TO M & I MARSHALL & ILSLEY BANK
To: MIDWEST INSTRUMENT COMPANY, INC.
Reel/Frame 032459/0285 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 6, 2014
From: HERAEUS ELECTRO-NITE CO., LLC
To: KEYSTONE SENSORS LLC
Reel/Frame 032398/0326 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 5, 2013
From: MIDWEST INSTRUMENT COMPANY, INC.
To: HERAEUS ELECTRO-NITE CO., LLC
Reel/Frame 029756/0505 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2011
From: VILLARREAL, ASCENCION Z., V; TURNER, PAUL A.; FALK, RICHARD A.
To: MIDWEST INSTRUMENT COMPANY
Reel/Frame 026330/0974 →
Continuity (1)
Related Publication 20110219889A1 · Sep 15, 2011