Composite positive electrode active material, electrode for lithium secondary battery including composite positive electrode active material, and lithium secondary battery
Provided are a composite positive electrode active material, an electrode for a lithium secondary battery including the composite positive electrode active material, and a lithium secondary battery, and more particularly, a composite positive electrode active material including lithium composite oxide, activated carbon, and carbon black, an electrode for a lithium secondary battery including the composite positive electrode active material, and a lithium secondary battery. The present disclosure may provide a lithium secondary battery having improved rate characteristics in a low-temperature atmosphere.
1. A composite positive electrode active material comprising:
80 to 98 parts by weight of a positive electrode active material expressed by the following Chemical Formula 1;
1 to 15 parts by weight of activated carbon; and
1 to 5 parts by weight of carbon black, based on 100 parts by weight of the composite positive electrode active material,
wherein a specific surface area of the activated carbon is in a range of 800 m 2 /g to 3000 m 2 /g and a specific surface area of the carbon black is in a range of 1000 m 2 /g to 2000 m 2 /g:
x Li 2 MnO 3 -(1− x )LiMO 2 [Chemical Formula 1]
where M is one or more selected from the group consisting of magnesium (Mg), nickel (Ni), cobalt (Co), chromium (Cr), aluminum (Al), vanadium (V), iron (Fe), copper (Cu), zinc (Zn), titanium (Ti), strontium (Sr), manganese (Mn), boron (B), and lanthanum (La), and 0<x<1.
2. The composite positive electrode active material as claimed in claim 1 , wherein a mixing ratio (w/w) of the carbon black to the activated carbon is in a range of 1:0.2 to 1:15.
3. The composite positive electrode active material as claimed in claim 1 , wherein the mixing ratio (w/w) of the carbon black to the activated carbon is in a range of 1:0.2 to 1:3.
4. An electrode for a lithium secondary battery comprising the composite positive electrode active material of claim 1 and a binder.
5. The electrode for a lithium secondary battery as claimed in claim 4 , wherein the binder is one or more selected from the group consisting of polyvinylidene fluoride, polytetrafluoroethylene, polyvinylchloride, polyvinylpyrrolidone, polyvinyl alcohol, carboxymethyl cellulose (CMC), starch, hydroxypropyl cellulose, polyethylene, polypropylene, a styrene-butadiene rubber, and a fluoro rubber.
6. The electrode for a lithium secondary battery as claimed in claim 4 , wherein a mixing ratio (w/w) of the composite positive electrode active material to the binder is in a range of 90:10 to 98:2.
7. A lithium secondary battery comprising the electrode for a lithium secondary battery of claim 4 .