Processes for recovering rubber from natural rubber latex

1. A process for recovering rubber from an aqueous non- Hevea natural rubber latex that contains natural rubber, water, extractables, and one or more additives, and is essentially free of lignocellulosic plant material, comprising the steps of:

contacting the latex with a separating solvent composition comprising at least one hydrocarbon solvent in an amount of 5% to 60% by weight and at least one organic polar solvent in an amount of 40 to 95% by weight whereby at least 75% of the natural rubber is separated from the water and a solution having a viscous rubber phase containing natural rubber and a reduced amount of extractables is formed;

isolating the viscous rubber phase; and

drying the viscous rubber phase to create a resultant natural rubber

wherein the resultant natural rubber has an amount of acetone extractables of 5% by weight or less.

2. A process as claimed in claim 1 further comprising, prior to drying the viscous rubber phase, the step of contacting the viscous rubber phase with at least one extracting solvent composition, wherein said at least one extracting solvent composition comprises at least one organic polar solvent.

3. A process as claimed in claim 2 wherein the amount of acetone extractables in the resultant natural rubber is 1% by weight or less.

4. A process as claimed in claim 3 wherein said at least one extracting solvent composition comprises acetone.

5. A process as claimed in claim 2 wherein, in said separating solvent composition, said at least one hydrocarbon solvent is present in an amount between 5% and 25% by weight and said at least one organic polar solvent is present in an amount between 75% and 95% by weight, said at least one extracting solvent composition comprises acetone, and the amount of acetone extractables in the resultant natural rubber is 1% by weight or less.

6. A process as claimed in claim 1 wherein the at least one organic polar solvent is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof.

7. A process as claimed in claim 1 wherein the at least one organic polar solvent is selected from the group consisting of ethanol, isopropanol, methanol, acetone, methyl ethyl ketone, and combinations thereof.

8. A process as claimed in claim 1 wherein the at least one hydrocarbon solvent is selected from the group consisting of alkanes having from 4 to 9 carbon atoms, cycloalkanes having from 5 to 10 carbon atoms, aromatics or alkyl substituted aromatics having from 6 to 12 carbon atoms, and combinations thereof.

9. A process as claimed in claim 1 wherein the at least one hydrocarbon solvent is selected from the group consisting of heptanes, nonane, pentane, hexane, cyclohexane, cyclopentane, benzene, xylene, toluene, and combinations thereof.

10. A process as claimed in claim 1 wherein the weight ratio of separating solvent composition to latex is 100:1 to 1:1.

11. A process as claimed in claim 1 wherein the weight ratio of separating solvent composition to latex is 20:1 to 1:1.

12. A process as claimed in claim 2 wherein the at least one organic polar solvent of the at least one extracting solvent composition is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof.

13. A process as claimed in claim 2 wherein the at least one organic polar solvent of the at least one extracting solvent composition is selected from the group consisting of ethanol, isopropanol, methanol, acetone, methyl ethyl ketone, and combinations thereof.

14. A process for recovering rubber from an aqueous non- Hevea natural rubber latex that contains natural rubber, water, extractables, and one or more additives, and is essentially free of lignocellulosic plant material, comprising the steps of:

contacting the latex with a separating solvent composition comprising hexane or cyclohexane in an amount of 5% to 60% by weight and acetone in an amount of 40 to 95% by weight whereby at least 75% of the natural rubber is separated from the water and a solution having a viscous rubber phase containing natural rubber and a reduced amount of extractables is formed;

isolating the viscous rubber phase; and

drying the viscous rubber phase to create a resultant natural rubber

wherein the resultant natural rubber has an amount of acetone extractables of 5% by weight or less.

15. A process for recovering rubber from an aqueous non- Hevea natural rubber latex that contains natural rubber, water, extractables, and one or more additives, and is essentially free of lignocellulosic plant material, comprising the steps of:

contacting the latex with a separating solvent composition comprising at least one hydrocarbon solvent in an amount of 5% to 60% by weight and at least one organic polar solvent in an amount of 40% to 95% by weight whereby at least 75% of the natural rubber is separated from the water and a solution having a viscous rubber phase containing natural rubber and a reduced amount of extractables is formed, wherein the weight ratio of separating solvent composition to latex is 100:1 to 1:1;

isolating the viscous rubber phase;

contacting the viscous rubber phase with at least one extracting solvent composition, wherein said at least one extracting solvent composition comprises at least one organic polar solvent; and

drying the viscous rubber phase to create a resultant natural rubber

wherein the resultant natural rubber has an amount of acetone extractables of 5% by weight or less.

16. A process as claimed in claim 15 wherein the at least one organic polar solvent of the separating solvent composition and of the at least one extracting solvent composition is selected from the group consisting of alcohols having from 1 to 8 carbon atoms, ketones having from 3 to 8 carbon atoms, and combinations thereof; and wherein the at least one hydrocarbon solvent is selected from the group consisting of alkanes having from 4 to 9 carbon atoms, cycloalkanes having from 5 to 10 carbon atoms, aromatics or alkyl substituted aromatics having from 6 to 12 carbon atoms, and combinations thereof.

17. A process as claimed in claim 16 wherein the at least one hydrocarbon solvent is cyclohexane or hexane and the at least one organic polar solvent of the separating solvent composition and of the at least one extracting solvent composition is acetone.

18. A process as claimed in claim 15 wherein the weight ratio of separating solvent composition to latex is 20:1 to 1:1.

19. A process as claimed in claim 15 wherein the amount of acetone extractables in the resultant natural rubber is 1% by weight or less.