Biodegradable polyester blends
Compositions comprising linear polyhydroxyalkanoates and biodegradable aromatic/aliphatic polyesters are disclosed, as well as methods for using same, and articles made therefrom.
1. A composition comprising:
a blend comprising biologically-produced poly-3-hydroxybutyrate, poly(3-hydroxybutyrate)-co-poly(4-hydroxybutyrate) with a 10-13% 4-hydroxybutyrate content, and poly(3-hydroxybutyrate)-co-poly(4-hydroxybutyrate) with a 26-35% 4-hydroxybutyrate content;
a biodegradable aromatic/aliphatic polyester; and
a nucleating agent, wherein the composition is a blend, wherein the biodegradable aromatic/aliphatic polyester is a co polymer of:
i) at least one aliphatic dicarboxylic acid; and/or
ii) at least one aromatic dicarboxylic acid; and
iii) a dihydroxy compound.
2. The composition of claim 1 , wherein the aliphatic dicarboxylic acid is selected from succinic acid, glutaric acid, dimethyl glutaric acid, adipic acid, sebacic acid or azelaic acid; wherein the aromatic dicarboxylic acid is selected from terephthalic acid or naphthalene dicarboxylic acid; and wherein the dihydroxy compound is selected from C 2 -C 6 alkanediols and C 5 -C 10 cycloalkanediols ethylene glycol, propylene glycol, 1,4-butanediol, 1,6 hexanediol, or 1,4 cyclohexanedimethanol.
3. The composition of claim 1 , wherein the biodegradable aromatic/aliphatic polyester is selected from:
polybutylene adipate terephthalate,
polyethylene adipate terephthalate,
polybutylene succinate terephthalate, and
polyethylene succinate terephthalate.
4. The composition of claim 1 , wherein the composition comprises at least two aromatic/aliphatic polyesters.
5. The composition of claim 1 , wherein from 5 to 95 percent by weight of the total polymer components of the composition is the biodegradable aromatic/aliphatic polyester or wherein from 10 to 50 percent by weight of the total polymer components of the composition is the biodegradable aromatic/aliphatic polyester.
6. The composition of claim 1 , wherein from 5 to 95 percent by weight of the composition is the blend of two or more biologically-produced polyhydroxyalkanoate copolymers.
7. The composition of claim 1 , wherein the biodegradable aromatic/aliphatic polyester is branched.
8. The composition of claim 1 , wherein from 50 to 90 percent by weight of the total polymer components of the composition is the blend of two or more linear biologically-produced polyhydroxyalkanoate copolymers.
9. The composition of claim 1 , wherein the nucleating agent is selected from cyanuric acid, carbon black, mica talc, silica, boron nitride, clay, calcium carbonate, synthesized silicic acid or a salt thereof, a metal salt of organophosphates and a kaolin aluminum hydroxy diphosphate or the nucleating agent has a chemical formula selected from the group consisting of
and combinations thereof, wherein each R1 is independently H, NR 2 R 2 , OR 2 , SR 2 , SOR 2 , SO 2 R 2 , CN, COR 2 , CO 2 R 2 , CONR 2 R 2 , NO 2 , F, Cl, Br, or I; and each R 2 is independently H or C 1 -C 6 alkyl.
10. The composition of claim 1 , wherein the blend of at least two or more linear biologically-produced polyhydroxyalkanoate copolymers comprises about 36% poly(3-hydroxybutyrate), blended with about 24% (poly(3-hydroxybutyrate-co-11%-poly(4-hydroxybutyrate), and about 40% (poly(3-hydroxybutyrate-co-28%-poly(4-hydroxybutyrate).
11. The composition of claim 1 , wherein the poly-3-hydroxybutyrate-co-4-hydroxybutyrate comprises a 10% 4-hydroxybutyrate content, an 11% 4-hydroxybutyrate content, a 12% 4-hydroxybutyrate content, or a 13% 4-hydroxybutyrate content.
12. A method of forming a polymer resin pellet comprising:
melting the composition of claim 1 under suitable conditions and forming a polymer resin pellet.
13. An article comprising the composition of claim 1 , wherein the article is in the form of a film.
14. A blown film comprising:
a blend comprising biologically-produced poly-3-hydroxybutyrate, poly(3-hydroxybutyrate)-co-poly(4-hydroxybutyrate) with a 10-13% 4-hydroxybutyrate content, and poly(3-hydroxybutyrate)-co-poly(4-hydroxybutyrate) with a 26-35% 4-hydroxybutyrate content;
a biodegradable aromatic/aliphatic polyester; and
a nucleating agent, wherein the composition is a blend, wherein the biodegradable aromatic/aliphatic polyester is a co polymer of:
i) at least one aliphatic dicarboxylic acid; and/or
ii) at least one aromatic dicarboxylic acid; and
iii) a dihydroxy compound.
15. The blown film of claim 14 , wherein the aliphatic dicarboxylic acid is selected from succinic acid, glutaric acid, dimethyl glutaric acid, adipic acid, sebacic acid or azelaic acid; wherein the aromatic dicarboxylic acid is selected from terephthalic acid or naphthalene dicarboxylic acid; and wherein the dihydroxy compound is selected from C 2 -C 6 alkanediols and C 5 -C 10 cycloalkanediols ethylene glycol, propylene glycol, 1,4-butanediol, 1,6 hexanediol, or 1,4 cyclohexanedimethanol.
16. The blown film of claim 14 , wherein the biodegradable aromatic/aliphatic polyester is selected from:
polybutylene adipate terephthalate,
polyethylene adipate terephthalate,
polybutylene succinate terephthalate, and
polyethylene succinate terephthalate.