Crucible for photovoltaics
A method for producing a workpiece comprising a layer of an additive-free silicon nitride includes providing a base body of the workpiece. A layer of a slip comprising a silicon powder is applied to an inside of the base body so as to obtain a coated base body. The coated base body is subjected to a reactive firing under nitrogen so as to convert the silicon powder to the additive-free silicon nitride.
1. A method for producing a workpiece comprising a layer of an additive-free silicon nitride, the method comprising:
providing a base body of the workpiece comprising a nitride-bonded silicon carbide;
applying a layer of a slip comprising a silicon powder to an inside of the base body so as to obtain a coated base body; and
subjecting the coated base body to a reactive firing under nitrogen so as to convert the silicon powder to the additive-free silicon nitride.
2. The method as recited in claim 1 , wherein the silicon nitride powder used for applying the layer has a particle size distribution of at least one of D 98 ≦10 μm and D 50 ≦2.5 μm, as measured with a Coulter Beckmann 13320 granulometer in accordance with a standard ISO 13320.
3. The method as recited in claim 1 , wherein the slip further comprises an inorganic fraction comprising the silicon powder.
4. The method as recited in claim 1 , wherein the silicon powder used for applying the layer has a particle size distribution of at least one of D 98 ≦20 μm and D 50 ≦4 μm, as measured with a Coulter Beckmann 13320 granulometer in accordance with a standard ISO 13320.
5. The method as recited in claim 1 , wherein the layer of the slip comprising the silicon powder is applied by at least one of a slip casting, a spraying process, and a brushing process.
6. The method as recited in claim 1 , wherein the reactive firing of the slip forms an insulating interlayer, the insulating interlayer having a thickness of from 0.2 to 2.0 mm after the reactive firing.
7. A workpiece comprising a layer of an additive-free silicon nitride, the workpiece being produced by a method comprising:
providing a base body of the workpiece comprising a nitride-bonded silicon carbide;
applying a layer of a slip comprising a silicon powder to an inside of the base body so as to obtain a coated base body; and
subjecting the coated base body to a reactive firing under nitrogen so as to convert the silicon powder to the additive-free silicon nitride.
8. A component produced from the workpiece as recited in claim 7 .
9. A method for producing a workpiece comprising a layer of an additive-free silicon nitride, the method comprising:
providing a base body of the workpiece comprising a material selected from the group consisting of a carbon fibre-based carbon (CFC), and a mixture a graphite and the carbon fibre-based carbon (CFC);
applying a layer of a slip comprising a silicon powder and a silicon nitride powder to an inside of the base body so as to obtain a coated base body; and
subjecting the coated base body to a reactive firing under nitrogen so as to convert the silicon powder to the additive-free silicon nitride.
10. The method as recited in claim 9 , wherein the slip comprises 55 to 90 wt.-% silicon nitride and 10 to 45 wt.-% silicon, based on the sum of silicon and silicon nitride.
11. The method as recited in claim 9 , wherein the silicon nitride powder used for applying the layer has a particle size distribution of at least one of D 98 ≦10 μm and D 50 ≦2.5 μm, as measured with a Coulter Beckmann 13320 granulometer in accordance with a standard ISO 13320.
12. The method as recited in claim 9 , wherein the silicon powder used for applying the layer has a particle size distribution of at least one of D 98 ≦20 μm and D 50 ≦4 μm, as measured with a Coulter Beckmann 13320 granulometer in accordance with a standard ISO 13320.
13. The method as recited in claim 9 , wherein the layer of the slip comprising the silicon powder is applied by at least one of a slip casting, a spraying process, and a brushing process.
14. The method as recited in claim 9 , wherein the reactive firing of the slip forms an insulating interlayer, the insulating interlayer having a thickness of from 0.2 to 2.0 mm after the reactive firing.
15. A workpiece comprising a layer of an additive-free silicon nitride, the workpiece being produced by a method comprising:
providing a base body of the workpiece comprising a material selected from the group consisting of a carbon fibre-based carbon (CFC), and a mixture a graphite and the carbon fibre-based carbon (CFC);
applying a layer of a slip comprising a silicon powder and a silicon nitride powder to an inside of the base body so as to obtain a coated base body; and
subjecting the coated base body to a reactive firing under nitrogen so as to convert the silicon powder to the additive-free silicon nitride.
16. A component produced from the workpiece as recited in claim 15 .