Methods and pressure vessels for solid-state microcellular processing of thermoplastic rolls or sheets
Disclosed herein are methods and pressure vessels for solid-state microcellular processing of thermoplastic rolls and sheets. In one embodiment, the present invention is directed to a method for making a gas impregnated interleaved roll, which method comprises: providing a pressure vessel having an internal pressure chamber and a rotatable shaft horizontally positioned within the pressure chamber; placing an interleaved roll about the rotatable shaft and within the pressure chamber, wherein the interleaved roll is made from a thermoplastic material sheet interleaved together with a gas-channeling material sheet; pressurizing the pressure chamber to a selected pressure; rotating the rotatable shaft having the interleaved roll thereabouts (thereby rotating the interleaved roll) while under pressure for a selected period of time; and depressurizing the internal chamber to yield the gas impregnated interleaved roll. In other embodiments, the invention is directed to multi-chambered pressure vessels for gas impregnation of thermoplastic rolls, sheets, and films.
1. A method for gas impregnation of an intermittently fed thermoplastic material sheet, comprising:
providing a pressure vessel having at least two outer pressure chambers sandwiching a central pressure chamber, wherein the central pressure chamber is separated from each of the two outer pressure chambers by respective interior sealable pass-through slots, wherein each of the interior sealable pass-through slots is defined by a rectangular opening having a pair of adjacently positioned confronting static seals for sealably engaging the intermittently fed thermoplastic material sheet, and wherein each of the two outer and central pressure chambers are separably pressurable to selected first, second, and third pressures, respectively;
pressurizing each of the two outer and central pressure chambers to the selected first, second, and third pressures; and
intermittently feeding the thermoplastic material sheet through each of the two outer and central pressure chambers by way of the interior sealable pass-through slots.
2. The method of claim 1 wherein the selected first, second, and third pressures each range from about 3.5 MPa to about 7.1 MPa.
3. The method of claim 2 wherein the selected first, second, and third pressures are each about the same.