Polyacrylic acid (salt)-type water absorbent resin and method for producing of same
A process for producing a water absorbent resin is provided with which it is possible to efficiently and inexpensively obtain a surface-crosslinked water-absorbing resin having excellent material properties, while ensuring high productivity. In continuous production scaled up to a large scale (in particular, 1 t/hr or more), the physical properties are improved and stabilized (for example, a reduction in standard deviation of the physical properties) by a surface crosslinking treatment to further improve absorption against pressure (AAP) and saline flow conductivity (SFC). The process for producing a polyacrylic acid (salt)-type water absorbent resin includes a surface treatment step in which after addition of a surface-crosslinking agent, a crosslinking reaction is conducted in a transverse type continuous stirring apparatus having stirring means including a feeding inlet and a discharging outlet of a water absorbent resin and one or more rotary shafts having with a plurality of stirring discs, and heating means, at a stirring-power index of the device of 3-15 W·hr/kg. (Stirring-power index)=((power consumption of apparatus at the time surface treatment)−(power consumption at the time of idling))×average retention time)/(treatment amount per unit time×average retention time).
1. A method for producing a polyacrylic acid (salt)-type water absorbent resin, comprising a step of preparing an aqueous monomer solution of an acrylic acid (salt), a step of continuously polymerizing the aqueous monomer solution, a step of finely shredding a hydrous gel-like crosslinked polymer during or after polymerization, a step of drying the obtained particulate hydrous gel-like crosslinked polymer, and a surface treatment step of adding and reacting a surface treatment agent to and with the dried water absorbent resin powder,
wherein crosslinking reaction is carried out at a stirring power index of 3 to 15 W·hr/kg in a transverse type continuous stirring apparatus having stirring means including a feeding inlet and a discharging outlet of a water absorbent resin and one or more rotary shafts having with a plurality of stirring discs, and heating means after the addition of the surface-crosslinking agent in the surface treatment step:
wherein
(stirring power index)=((power consumption of apparatus at the time surface treatment)−(power consumption at the time of idling))×average retention time)/(treatment amount per unit time×average retention time).
2. The production method according to claim 1 further comprising forcibly cooling the water absorbent resin powder by using a transverse type continuous stirring apparatus having a stirring power index of 5 to 13 (W·hr/kg) after the heating treatment.
3. The production method according to claim 1 , wherein the surface treatment step has two or more lines for one line in the polymerization step.
4. The production method according to claim 1 , wherein a periodical shielding apparatus is installed in the inlet and/or the outlet of the transverse type continuous stirring apparatus to be used in the surface treatment step.
5. The production method according to claim 1 , wherein the transverse type continuous stirring apparatus to be used in the surface treatment step has a downward inclined angle of 0.1 to 5)(°).
6. The production method according to claim 1 , wherein the transverse type continuous stirring apparatus to be used in the surface treatment step has a mass surface area ratio defined below of 100 (kg/m 2 /hr) or lower:
wherein,
(mass surface area ratio)=(mass flow rate of water absorbent resin per unit time)/(heat transfer area of apparatus).
7. The production method according to claim 1 , wherein the transverse type continuous stirring apparatus to be used in the surface treatment step has an aspect ratio of 1.5 to 5.
8. The production method according to claim 1 , wherein the transverse type continuous stirring apparatus to be used in the surface treatment step has scraping blades.
9. The production method according to claim 1 , wherein the transverse type continuous stirring apparatus to be used in the surface treatment step has a surface roughness (Rz) in the inner face of 800 (nm) or lower.
10. The production method according to claim 1 , wherein the bulk specific gravity of the polyacrylic acid (salt)-type water absorbent resin is 0.50 to 0.75 (g/cm 3 ).
11. The production method according to claim 1 , wherein a surfactant is added to the polyacrylic acid (salt)-type water absorbent resin.
12. The production method according to claim 1 , wherein the inside of the transverse type continuous stirring apparatus is kept in slightly reduced pressure.
13. The production method according to claim 1 , wherein a heat medium for the transverse type continuous stirring apparatus to be used in the surface treatment step is pressurized steam.
14. The production method according to claim 1 , wherein the surface treatment step is carried out by adding a dehydration reactive crosslinking agent and heating treatment at 150 to 250° C.
15. The production method according to claim 1 , wherein the surface treatment step is carried out by adding an organic surface-crosslinking agent and/or a polyvalent metal salt.
16. The production method according to claim 1 , wherein the polymerization step is carried out by continuous kneader polymerization or continuous belt polymerization.
17. The production method according to claim 1 , wherein the polyacrylic acid (salt)-type water absorbent resin has 25 (×10 −7 ·cm 3 ·s·g −1 ) or higher of flow conductivity of physiological saline solution (SFC).