Aerosol fabrication methods for monodisperse nanoparticles
Exemplary embodiments provide materials and methods for forming monodisperse particles. In one embodiment, the monodisperse particles can be formed by first spraying a nanoparticle-containing dispersion into aerosol droplets and then heating the aerosol droplets in the presence of a shell precursor to form core-shell particles. By removing either the shell layer or the nanoparticle core of the core-shell particles, monodisperse nanoparticles can be formed.
1. A method of forming monodisperse particles comprising:
forming a plurality of aerosol droplets by spraying a dispersion comprising a plurality of nanoparticles disposed in a solvent, the solvent comprising hydrocarbon;
heating the plurality of aerosol droplets at a heating temperature to induce hydrocarbon pyrolysis such that a carbonaceous shell layer is coated on each of the plurality of nanoparticles; and
removing the carbonaceous shell layer to form monodisperse nanoparticles.
2. The method of claim 1 , wherein the heating temperature is in a range from about 600° C. to about 1600° C. to induce hydrocarbon pyrolysis.
3. The method of claim 1 , further comprising controlling a thickness of the carbonaceous shell layer in a range from about 2 nm to about 1000 nm.
4. The method of claim 1 , wherein each of the plurality of nanoparticles comprises a material selected from the group consisting of metal, metal oxide, metal nitride, metal alloy, and combinations thereof.
5. The method of claim 1 , wherein the plurality of nanoparticles comprise one or more metals selected from the group consisting of Ni, Au, Ag, Pd, Pt, Cu, Li, Ga, Zn, Ce, Cr, Ge, Fe, Co, Ti, Mn, V, Sn, and combinations thereof.
6. The method of claim 1 , further comprising calcinating the plurality of nanoparticles prior to removing the carbonaceous shell layer.
7. The method of claim 6 , wherein the calcination devitrifies the plurality of nanoparticles comprising amorphous silica into a plurality of single-crystalline α-cristobalite nanospheres to form the monodisperse nanoparticles.
8. The method of claim 6 , wherein the plurality of nanoparticles comprise magnetic metal alloy nanoparticles formed of FePt, wherein the magnetic FePt nanoparticles are monodisperse and in super-paramagnetic L10 phase.
9. The method of claim 1 , wherein the step of removing the carbonaceous shell layer comprises a low-temperature oxidation or a wet oxidation process.
10. The method of claim 1 , wherein the step of spraying a plurality of nanoparticles into a plurality of aerosol droplets comprises using an atomizer.
11. The method of claim 1 , wherein the solvent comprises a hydrophilic solvent, a hydrophobic solvent, and combinations thereof.
12. A method of forming monodisperse particles comprising:
forming a plurality of aerosol droplets by spraying a dispersion comprising a plurality of nanoparticles disposed in a solvent;
heating the plurality of aerosol droplets in a presence of one or more salts at a temperature to generate salt vapor, wherein the salt vapor is deposited as a salt shell layer on each nanoparticle of the plurality of nanoparticles; and
removing the salt shell layer to form monodisperse nanoparticles.
13. The method of claim 12 , wherein the plurality of nanoparticles comprise a material selected from the group consisting of metal, metal oxide, metal nitride, metal alloy, and combinations thereof.
14. The method of claim 12 , wherein each of the one or more salts comprises LiCl, NaCl, KCl, LiBr, NaBr, KBr, or combinations thereof.
15. The method of claim 12 , wherein the salt shell layer comprises a crystal salt.
16. The method of claim 12 , further comprising controlling a thickness of the salt shell layer ranging from about 2 nm to about 1000 nm.
17. The method of claim 12 , further comprising calcinating the plurality of nanoparticles prior to removing the salt shell layer.
18. The method of claim 17 , wherein the calcination devitrifies the plurality of nanoparticles comprising amorphous silica into a plurality of single-crystalline α-cristobalite nanospheres to form the monodisperse nanoparticles.
19. The method of claim 17 , wherein the plurality of nanoparticles comprise magnetic metal alloy nanoparticles formed of FePt, wherein the magnetic FePt nanoparticles are monodisperse and in super-paramagnetic L10 phase.
20. A method of forming monodisperse particles comprising:
forming a plurality of aerosol droplets by spraying a dispersion comprising a plurality of nanoparticles disposed in a solvent;
heating the plurality of aerosol droplets in a presence of one or more of a metal-containing precursor, a hydrocarbon solvent, and combinations thereof at a heating temperature such that a shell layer comprising a metal shell layer, a metal alloy shell layer, a carbonaceous shell layer, or combinations thereof is deposited on each nanoparticle of the plurality of nanoparticles; and
removing the each nanoparticle of the plurality of nanoparticles from the shell layer to form a plurality of hollow particles that are monodisperse.
21. The method of claim 20 , wherein the plurality of hollow carbon-containing particles have an average particle size ranging from about 5 nm to about 10 μm.
22. The method of claim 20 , wherein the plurality of nanoparticles comprise a metal oxide comprising SiO 2 , while the shell layer of the hollow particles comprises SiC, metal, metal alloy, carbon, or combinations thereof.