Method and apparatus of producing composite for carbon dioxide separation
There is provided a method of producing a composite that separates carbon dioxide that has a carbon dioxide separating film on a support includes preparing, at greater than or equal to 50° C., a coating liquid for carbon dioxide separating film formation that contains a water absorbent polymer, a carbon dioxide carrier and a gelling agent, and that gels, after being left at 12° C. at a solution film thickness of less than or equal to 1 mm, within 120 seconds and liquid not dropping-off due to gravity; coating the coating liquid on a strip-shaped support; cooling, at less than or equal to 12° C., a coated film obtained by the coating, and obtaining a gel film; and drying the gel film at least by warm air, and obtaining a carbon dioxide separating film, wherein, from coating to drying are carried out continuously while conveying the support in a given direction.
1. A method of producing a composite that separates carbon dioxide that has a carbon dioxide separating film on a support, comprising in the following order:
preparing, at greater than or equal to 50° C., a coating liquid for carbon dioxide separating film formation that contains a water absorbent polymer, a carbon dioxide carrier and a gelling agent, and that has the property of, after being left at 12° C. at a solution film thickness of less than or equal to 1 mm but greater than 0 mm, gelling within 120 seconds and liquid not dropping-off due to gravity;
coating the coating liquid on a strip-shaped support;
cooling, at less than or equal to 12° C., a coated film obtained by the coating, and obtaining a gel film; and
drying the gel film at least by warm air, and obtaining a carbon dioxide separating film,
wherein, from the coating to the drying are carried out continuously while conveying the support in a given direction.
2. The method of producing a composite that separates carbon dioxide of claim 1 , wherein a conveying speed of the support from the coating to the drying is greater than or equal to 20 m/min.
3. The method of producing a composite that separates carbon dioxide of claim 1 , wherein, in the preparing of the coating liquid, the coating liquid is prepared at 60 to 85° C.
4. The method of producing a composite that separates carbon dioxide of claim 1 , wherein, in the drying, an air speed of the warm air is 10 to 40 m/min.
5. The method of producing a composite that separates carbon dioxide of claim 1 , wherein, in the drying, a temperature of the warm air is 40 to 60° C.
6. The method of producing a composite that separates carbon dioxide of claim 1 , wherein the gelling agent is a polysaccharide.
7. The method of producing a composite that separates carbon dioxide of claim 1 , wherein the gelling agent is an agar.
8. The method of producing a composite that separates carbon dioxide of claim 1 , wherein the carbon dioxide carrier has an alkali metal carbonate.
9. The method of producing a composite that separates carbon dioxide of claim 1 , wherein the carbon dioxide carrier is a compound containing cesium.