Method for producing water-absorbent resin particles and water-absorbent resin particles
The present invention provides a method for producing water-absorbent resin particles which show an excellent water absorption rate and high equilibrium swelling capacity and which have an appropriate particle size to be excellent in handleability, and water-absorbent resin particles obtained by the method. The present invention is a method for producing water-absorbent resin particles by reversed phase suspension polymerization of a water-soluble ethylenically unsaturated monomer, the method including the steps of: (A) first reversed phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a petroleum hydrocarbon dispersion medium using a water-soluble radical polymerization initiator, in the absence of an internal crosslinking agent and in the presence of a surfactant having an HLB of 8 to 12; (B) intermediate crosslinking reaction by adding an intermediate crosslinking agent; (C) second reversed phase suspension polymerization of a water-soluble ethylenically unsaturated monomer added to the petroleum hydrocarbon dispersion medium containing the surfactant dissolved therein using a water-soluble radical polymerization initiator in the absence of an internal crosslinking agent, thereby producing a water-absorbent resin precursor; and (D) post crosslinking reaction of the water-absorbent resin precursor preliminary adjusted to have a moisture content of 30 to 100% by mass relative to a water-soluble ethylenically unsaturated monomer component in the water-absorbent resin precursor.
1. A method for producing water-absorbent resin particles by reversed phase suspension polymerization of a water-soluble ethylenically unsaturated monomer, the method comprising the steps of:
(A) first reversed phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a petroleum hydrocarbon dispersion medium using a water-soluble radical polymerization initiator, in the absence of an internal crosslinking agent and in the presence of a surfactant having an HLB of 8 to 12;
(B) intermediate crosslinking reaction by adding an intermediate crosslinking agent;
(C) second reversed phase suspension polymerization of a water-soluble ethylenically unsaturated monomer added to the petroleum hydrocarbon dispersion medium containing the surfactant dissolved therein using a water-soluble radical polymerization initiator in the absence of an internal crosslinking agent, thereby producing a water-absorbent resin precursor; and
(D) post crosslinking reaction of the water-absorbent resin precursor preliminary adjusted to have a moisture content of 30 to 100% by mass relative to a water-soluble ethylenically unsaturated monomer component in the water-absorbent resin precursor.
2. The method for producing water-absorbent resin particles according to claim 1 ,
wherein
the surfactant having an HLB of 8 to 12 is at least one compound selected from the group consisting of a sorbitan fatty acid ester, a polyglycerol fatty acid ester, and a sucrose fatty acid ester.
3. The method for producing water-absorbent resin particles according to claim 1 ,
wherein
the intermediate crosslinking agent is a glycidyl ether compound.
4. The method for producing water-absorbent resin particles according to claim 1 ,
wherein
the amount of the intermediate crosslinking agent added is 0.0001 to 0.026 mol % relative to the total molar amount of the water-soluble ethylenically unsaturated monomers.
5. Water-absorbent resin particles produced by the method for producing water-absorbent resin particles according to claim 1 .
6. The water-absorbent resin particles according to claim 5 ,
wherein
the water-absorbent resin particles have equilibrium swelling capacity of 12 to 28 mm, a water absorption rate of 1 to 5 seconds, saline retention capacity of 20 to 60 g/g, and a median particle size of 100 to 400 μm.