Compound and organic device employing same
The compounds represented by the following general formula have excellent properties as a charge transport material. In the formula, R 1 to R 3 represent a substituent, n1 and n2 indicate an integer of from 0 to 5, n3 indicates an integer of from 0 to 4, X represents a linking group of —O—, —S—, —SO 2 —, —CS—, —R 4 —, —C(R 5 )(R 6 )—, —PO(R 7 )—, —Si(R 8 )(R 9 )—, >PO—, >Si(R 10 )— or >Si<, m is an integer of from 2 to 4, R 4 represents an aliphatic cyclic linking group, and R 5 to R 10 represent a hydrogen atom, an alkyl group, an aryl group, etc.
1. A compound represented by the following general formula (1):
wherein R 1 , R 2 and R 3 each independently represent a substituent, n1 and n2 each independently indicate an integer of from 0 to 5, n3 indicates an integer of from 0 to 4, X represents a linking group having any of the following structures, m is equal to the valence of the linking group X and indicates an integer of from 2 to 4;
wherein R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 , R 9 and R 10 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group; provided that when X is —O—, this links at the 3,3′-positions of the triphenylphosphine oxide structure of the general formula (1).
2. A compound according to claim 1 , which is represented by the following general formula (2 ):
wherein R 11 ,R 12 , R 13 , R 21 , R 22 and R 23 each independently represent a substituent, n11, n12, n21 and n22 each independently indicate an integer of from 0 to 5, n13 and n23 each independently indicate an integer of from 0 to 4, X 11 represents a linking group having any of the following structures;
wherein R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 and R 9 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group; provided that when X is —O—, this links at the 3,3′-positions of the triphenylphosphine oxide structure of the general formula (1).
3. A compound according to claim 1 , which is represented by the following general formula (2-1):
wherein R 11 ,R 12 , R 13 , R 21 , R 22 and R 23 each independently represent a substituent, n11, n12, n21 and n22 each independently indicate an integer of from 0 to 5, n13 and n23 each independently indicate an integer of from 0 to 4, X 21 represents a linking group having any of the following structures;
wherein R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 and R 9 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group.
4. A compound according to claim 1 , which is represented by the following general formula (2-2):
wherein R 11 ,R 12 , R 13 , R 21 , R 22 and R 23 each independently represent a substituent, n11, n12, n21 and n22 each independently indicate an integer of from 0 to 5, n13 and n23 each independently indicate an integer of from 0 to 4, X 22 represents a linking group having any of the following structures;
wherein R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 and R 9 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group.
5. A compound according to claim 1 , which is represented by the following general formula (2-3):
wherein R 11 , R 12 , R 13 , R 21 , R 22 and R 23 each independently represent a substituent, n11, n12, n21 and n22 each independently indicate an integer of from 0 to 5, n13 and n23 each independently indicate an integer of from 0 to 4, X 23 represents a linking group having any of the following structures;
wherein R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 and R 9 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group.
6. The compound according to claim 1 , wherein the linking group has the following structure
7. The compound according to claim 1 , wherein the linking group has the following structure
8. The compound according to claim 1 , which has a lowest excited triplet energy level at 77°K of not lower than 2.80 eV.
9. The compound according to claim 1 , which has a lowest excited triplet energy level at 77°K of not lower than 2.95 eV.
10. A charge transport material comprising a compound represented by the following formula (1):
wherein R 1 , R 2 and R 3 each independently represent a substituent, n1 and n2 each independently indicate an integer of from 0 to 5, n3 indicates an integer of from 0 to 4, X represents a linking group having any of the following structures, m is equal to the valence of the linking group X and indicates an integer of from 2 to 4;
wherein R 4 represents a substituted or unsubstituted aliphatic cyclic linking group; R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 , R 9 and R 10 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group; provided that when X is —O—, this links at the 3,3′-positions of the triphenylphosphine oxide structure of the general formula (1).
11. An organic device using a compound represented by the following formula (1):
wherein R 1 , R 2 and R 3 each independently represent a substituent, n1 and n2 each independently indicate an integer of from 0 to 5, n3 indicates an integer of from 0 to 4, X represents a linking group having any of the following structures, m is equal to the valence of the linking group X and indicates an integer of from 2 to 4;
wherein R 4 represents a substituted or unsubstituted aliphatic cyclic linking group; R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 , R 9 and R 10 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group; provided that when X is —O—, this links at the 3,3′-positions of the triphenylphosphine oxide structure of the general formula (1).
12. An organic electroluminescence element using a compound represented by the following formula (1):
wherein R 1 , R 2 and R 3 each independently represent a substituent, n1 and n2 each independently indicate an integer of from 0 to 5, n3 indicates an integer of from 0 to 4, X represents a linking group having any of the following structures, m is equal to the valence of the linking group X and indicates an integer of from 2 to 4;
wherein R 4 represents a substituted or unsubstituted aliphatic cyclic linking group; R 5 and R 6 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; R 8 , R 9 and R 10 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; at least one of R 8 and R 9 is a hydrogen atom, or a substituted or unsubstituted alkyl group; provided that when X is —O—, this links at the 3,3′-positions of the triphenylphosphine oxide structure of the general formula (1).