Peroxide cured TPV
Thermoplastic elastomer compositions and methods for making same. The elastomer composition can include at least one partially cured rubber component that is an ethylene-alpha-olefin-vinyl norbornene elastomeric polymer, and at least one thermoplastic component. The rubber component is at least partially cured using a peroxide curative in an amount effective to yield a cure level of the rubber component of at least 85%. The rubber component has a molecular weight distribution (MWD) less than 6, and a branching index greater than 0.60.
1. A thermoplastic elastomer,comprising:
about 60 wt % to about 90 wt % of at least partially cured metallocene-produced ethylene-propylene-vinyl norbornene elastomeric rubber component, wherein the vinyl norbornene content of the rubber component is 0.2 wt % to 1.5 wt % and the ethylene content is 50 wt % to 80 wt %; and
about 10 wt % to about 40 wt % of at least one thermoplastic component;
wherein the rubber component is at least partially cured using a peroxide curative to yield a cure level of the rubber component of at least 95%,
wherein the rubber component has a molecular weight distribution (MWD) of less than 4, a weight average molecular weight (Mw) of from 50,000 to 150,000 g/mole, a branching index greater than 0.70, and a Mooney viscosity, ML(1+4 at 125° C.), as determined according to ASTM D1646, of 10 to 26.2; and
wherein the thermoplastic elastomer has (as determined according to ASTM D412):an ultimate tensile stength of 3.6-5.1 MPa, an elongation at break of 124% to 222%, and a tension set of 10.0% to 23.0%.
2. The thermoplastic elastomer of claim 1 , wherein the thermoplastic component is polypropylene having a heat of fusion of less than 210 J/g and greater than 90 J/g.
3. The thermoplastic elastomer of claim 1 , wherein the ethylene content of the rubber component is about 50 wt % to about 70 wt %.
4. The thermoplastic elastomer of claim 1 , wherein the thermoplastic component is selected from the group consisting of theroplastic homopolymers and copolymers of propylene, polybutylene, homopolymers and copolymers of ethylene, polyethylene terephthalate, polybutylene terephthalate, polyamides, and mixtures thereof.
5. The thermoplastic elastomer of claim 1 , wherein the amount of peroxide curative is about 2 phr to about 5 phr.
6. The thermoplastic elastomer of claim 1 , further comprising less than 5.0 phr oil.
7. The thermoplastic elastomer of claim 1 , wherein the thermoplastic elastomer has a compression set of about 80% or less, as measured after 22hours at 100° C. by test method ASTM D 395B.
8. A thermoplastic elastomer, comprising:
about 60 wt % to about 90 wt % of at least partially cured metallocene-produced ethylene-propylene-vinyl norbomene elastomeric rubber component, wherein the vinyl norbomene content of the rubber component is 0.2 wt % to 1.5 wt % and the ethylene content is 50 wt % to 80 wt %;
about 10 wt % to about 40 wt % of at least one thermoplastic component comprising polypropylene having a heat of fusion of less than 210 J/g and greater than 90 J/g; and
less than 5.0 phr oil,
wherein the rubber component is at least partially cured using a peroxide curative to yield a cure level of the rubber component of at least 95.0%,
wherein the rubber component has molecular weight distribution (MWD) less than 4, a weight average molecular weight (Mw) of from 50,000 to 150,000 g/mole, a branching index of 0.70 or more, and a Mooney viscosity, ML(1+4 at 125° C.), as determined according to ASTM D1646, of 10 to 26.2, and
wherein the thermoplastic elastomer has a compression set of about 80% or less, as measured after 22 hours at 100° C. by test method ASTM D 395B, an untimate tensile strength (ASTM D412) of 3.6-5.1 MPa, an elongation at break (ASTM D412) of 124% to 222%, and a tension set (ASTM D412) of 10.0% to 23.0%.