Process for preparing 2.2-dibromomalonamide
The present invention generally relates to a process for preparing 2,2-dibromomalonamide from 2,2-dibromo-3-cyanoacetamide.
1. A process for preparing 2,2-dihromomalonamide, the process comprising contacting together an amount of 2,2-dibromo-3-cyanoacetamide and an effective amount of a nitrile-arnide-conversion composition to form a reaction mixture, the contacting being performed in such a way so as to produce 2,2-dibromomalonamide and wherein the process further comprises
a. obtaining a mother liquor from the reaction mixture:
b. preparing another nitrile-amide-conversion composition comprising most of the mother liquor;
c. contacting the other nitTile-amide-conversion comprising the mother liquor to another amount of 2,2-dibrotno-3-cvanoacetamide to form another reaction mixture, the contacting the other nitrile-amide-conversion comprising the mother liquor to another amount of 2,2-dibromo-3-cvanoacetamide being performed in such a way no as to produce additional 2,2-dibromomalonamide.
2. The process as in claim 1 , the process further comprising maintaining pH of the reaction mixture during the contacting step at less than pH 9.0.
3. The process as in claim 2 , the process further comprising maintaining pH of the reaction mixture during the contacting step at a pH from pH 4.0 to less than pH 9.0.
4. The process as in claim 3 , the process further comprising maintaining pH of the reaction mixture during the contacting step at a pH from pH 5.5 to pH 7.0.
5. The process as in claim 1 , each contacting step independently producing the 2,2-dibromomalonamide in 75 percent yield or higher based on an amount of 2,2-dibromo-3-cyanoacetamide that has reacted.