Optical film
Provided is an optical film including a polyurethane coating layer including high refractive inorganic materials to lower reflectivity without causing a rainbow phenomenon.
1. An optical film, comprising:
a biaxially stretched polyester base film; and
a polyurethane coating layer on one surface or both surfaces of the base film, wherein the polyurethane coating layer is formed from a polyurethane coating composition comprising a polyurethane binder having a refractive index of 1.54 to 1.59 and a high refractive inorganic filler having a refractive index of 2.0 or more,
wherein the polyurethane binder is prepared by reacting a polyol with an isocyanate compound including at least one aromatic isocyante compound of the following Formula 1:
OCN—Ar—NCO Formula 1
wherein Ar is naphthalene or phenalene.
2. The optical film of claim 1 , wherein the high refractive inorganic filler is one or a mixture of two or more selected from the group consisting of ZnO, TiO 2 , CeO 2 , SnO 2 , and ZrO 2 .
3. The optical film of claim 1 , wherein the amount of the aromatic isocyanate compound is 25 to 90 wt % based on the total content of the isocyanate compound.
4. The optical film of claim 1 , wherein the polyurethane coating composition has a total solid content of 2 to 10 wt %;
wherein the polyurethane coating composition comprises 5 to 30 wt % of the polyurethane binder, 0.5 to 30 wt % of the high refractive inorganic filler which has a solid content of 5 to 40 wt %, 0.1 to 0.4 wt % of wetting agent, and 0.1 to 0.5 wt % of silica having an average particle size of 100 to 200 nm; and
wherein said high refractive inorganic filler is dispersed in water.
5. The optical film of claim 4 , wherein the polyurethane binder is an aqueous polyurethane binder having a solid content of 15 to 30 wt %; and wherein the polyurethane binder comprises water and a reactive emulsifier having ionic groups.
6. The optical film of claim 4 , wherein the high refractive inorganic filler has an average particle size less than 30 nm.
7. The optical film of claim 1 , wherein the thickness of the polyurethane coating layer in dry state is 15 to 150 nm.
8. The optical film of claim 1 , wherein the base film is a polyethyleneterephthalate film.
9. The optical film of claim 8 , wherein the optical film further includes a hard coating layer.