Light-emitting element, light-emitting device, display device, electronic device, and lighting device
View Patent ↗An object is to provide a light-emitting element which includes an exciplex being used as an energy donor capable of efficiently transferring energy to a substance exhibiting thermally activated delayed fluorescence. The exciplex comprises two kinds of substances and its singlet and triplet excited states are close to each other. Thus, by making light emission of the exciplex overlap with an absorption band on the longest wavelength side which corresponds to absorption by the substance exhibiting thermally activated delayed fluorescence, i.e., an energy acceptor, in a singlet excited state, it becomes possible to achieve efficient energy transfer from a singlet excited state of the exciplex to a singlet excited state of the substance exhibiting thermally activated delayed fluorescence, and it also becomes possible to achieve efficient energy transfer from a triplet excited state of the exciplex to a triplet excited state of the substance exhibiting thermally activated delayed fluorescence.
1. A light-emitting device comprising:
a pair of electrodes; and
a light-emitting layer between the pair of electrodes, the light-emitting layer comprising a first organic compound, a second organic compound, and a light-emitting substance which exhibits thermally activated delayed fluorescence,
wherein an emission of an exciplex of the first organic compound and the second organic compound overlaps with an absorption band of the light-emitting substance.
2. The light-emitting device according to claim 1 , wherein the emission overlaps with the absorption band on the lowest energy side.
3. The light-emitting device according to claim 2 , wherein a difference in energy between a peak wavelength of the absorption band and a peak wavelength of the emission is 0.2 eV or less.
4. The light-emitting device according to claim 1 , wherein a difference in energy between peak wavelengths of fluorescence and phosphorescence of the light-emitting substance is 0.2 eV or less.
5. The light-emitting device according to claim 1 , wherein the first organic compound has an electron-transport property, and the second organic compound has a hole-transport property.
6. The light-emitting device according to claim 1 , wherein the first organic compound is a π-deficient heteroaromatic compound, and the second organic compound is a π-excessive heteroaromatic compound or an aromatic amine compound.
7. An electronic device comprising the light-emitting device according to claim 1 .
8. A lighting device comprising the light-emitting device according to claim 1 .
9. A light-emitting device comprising:
a pair of electrodes; and
a light-emitting layer between the pair of electrodes, the light-emitting layer comprising a first organic compound, a second organic compound, and a light-emitting substance which exhibits thermally activated delayed fluorescence,
wherein a difference in energy between peak wavelengths of fluorescence and phosphorescence of the light-emitting substance is 0.2 eV or less, and
wherein the light-emitting substance comprises a π-excessive heteroaromatic ring and a π-deficient heteroaromatic ring.
10. The light-emitting device according to claim 9 , wherein a difference in equivalent energy between peak wavelengths of fluorescence and phosphorescence of an exciplex of the first organic compound and the second organic compound is 0.2 eV or less.
11. The light-emitting device according to claim 9 , wherein the first organic compound has an electron-transport property, and the second organic compound has a hole-transport property.
12. The light-emitting device according to claim 9 , wherein the first organic compound is a π-deficient heteroaromatic compound, and the second organic compound is a π-excessive heteroaromatic compound or an aromatic amine compound.
13. An electronic device comprising the light-emitting device according to claim 9 .
14. A lighting device comprising the light-emitting device according to claim 9 .