Polyamide composition for surface-mounted components
A polyamide composition for surface-mounted components is described. Also described are compositions for surface-mounted components (SMCs) including a semiaromatic polyamide modified by a hydroxyaromatic compound, reinforcing fillers, and a flame retardant. Further, the compositions have many advantages linked to the uses thereof in lead-free reflow soldering processes, in particular a good dimensional stability and a blistering resistance during the use of articles produced from these compositions.
1. A component for surface mounting obtained at least from a composition comprising at least a semiaromatic polyamide modified by an aromatic hydroxyl compound, a fibrous filler; and a flame retardant
wherein the aromatic hydroxyl compound is represented by the following formula (I):
(HO) x —Z—(F) n (I)
and wherein:
Z is a multivalent aromatic or arylaliphatic hydrocarbon radical;
x is from 1 to 10;
F is an acid, aldehyde, amine or ketone function that can bond to an acid or amine function of the polyamide monomers; and
n is from 1 and 5.
2. The component as defined in claim 1 , wherein 5 mol % to 50 mol % of the monomers used in the semiaromatic polyamide are monomers comprising aromatic groups, including the aromatic hydroxyl compound.
3. The component as defined in claim 1 , wherein the polyamide is selected from the group consisting of: polyamide 6T, polyamide 66/6T, polyamide 6I, polyamide 66/6I, polyamide 6T/6I, copolyamide 6/6T of differing molar compositions and blends thereof.
4. The component as defined in claim 1 , wherein the polyamide has a melting point of from 150° C. to 340°C.
5. The component as defined in claim 1 the composition comprises 30% to 75% by weight of polyamide, with respect to the total weight of the composition.
6. The component as defined in claim 1 , wherein the aromatic hydroxyl compound has at least one function that can react with the functions of the polyamide or the polyamide monomers.
7. The component as defined in claim 1 , wherein Z is a multivalent radical selected from the group consisting of: benzene, methylbenzene, a naphthalene, a biphenyl, a diphenyl ether, a diphenyl sulfide, a diphenyl sulfone, a ditolyl ether, a xylylene, a diethylbenzene and a pyridine.
8. The component as defined in claim 1 , wherein the aromatic hydroxyl compound is selected from the group consisting of: a 2-hydroxyterephthalic acid, a 5-hydroxyisophthalic acid, a 4-hydroxyisophthalic acid, a 2,5-dihydroxyterephthalic acid, a 4-hydroxyphenylacetic acid or a gallic acid, a L-tyrosine, a 4-hydroxyphenylacetic acid, a 3,5-diaminophenol, a 5-hydroxy-m-xylylenediamine, a 3-aminophenol, a 3-amino-4-methylphenol and a 3-hydroxy-5-aminobenzoic acid.
9. The component as defined in claim 1 , wherein the fibrous filler is selected from the group consisting of glass fiber, a carbon fiber, a natural fiber, an aramid fiber, nanotube, hemp and flax.
10. The component as defined in claim 1 , wherein the composition comprises 15% to 50% by weight of reinforcing filler, with respect to the total weight of the composition.
11. The component as defined in claim 1 , wherein the flame retardant is comprised of phosphorus and is selected from the group consisting of: a phosphine oxide, a phosphonic acid or a salt thereof, a phosphinic acid or a salt thereof, a cyclic phosphonate, an organic phosphate, an inorganic phosphate, and a red phosphorus.
12. The component as defined in claim 1 , wherein the flame retardant is an organic nitrogen flame retardant selected from the group consisting of: a triazine, a cyanuric acid, an isocyanuric acid, a melamine, a melamine oxalate, a phthalate, a borate, a sulfate, a phosphate, a polyphosphate, a pyrophosphate, a condensed melamine product, a tris(hydroxyethyl) isocyanurate, a benzoguanamine, a guanidine, a allantoin, and a glycoluril.
13. The component as defined in claim 1 , wherein the flame retardant is a flame retardant comprising a brominated derivative selected from the group consisting of: a PBDPO (a polybromodiphenyl oxide), a BrPS (a brominated polystyrene and polybromostyrene), poly(pentabromobenzyl acrylate), brominated indane, tetradecabromodiphenoxybenzene, 1,2-bis(pentabromophenyl)ethane, tetrabromobisphenol A and a brominated epoxy oligomer.
14. The component as defined in claim 1 , wherein the composition comprises 5% to 40% by weight of flame retardants, with respect to the total weight of the composition.
15. A process for assembling a component as defined in claim 1 on a surface, the process comprising soldering and/or brazing.