Composite materials comprising propylene-based polymer blend coatings
Coated composite materials and methods for their manufacture are described. In particular, embodiments of the present invention include a substrate material coated on at least a portion with a polymer blend comprising from about 50 to about 95 wt % of a propylene-based copolymer comprising propylene and from about 3 to about 40 wt % ethylene-derived units and from about 5 to about 50 wt % of a hydrocarbon resin. The propylene-based copolymer has a melting temperature less than about 110° C., a heat of fusion less than about 75 J/g, and a triad tacticity greater than 75%. The coating compositions are suitable for hot fill applications, soft to the touch and have a low coefficient of friction, low haze, and are able to retain textural design features. Methods for forming such coated composite materials are also provided.
1. A process for forming a composite material, comprising:
applying a coating composition onto at least a portion of a plastic substrate; wherein the coating composition is a polymer blend comprising from about 50 to about 95 wt % of one or more propylene-based copolymers and from 30 wt % to about 50 wt % of one or more hydrocarbon resins, wherein at least one propylene-based copolymer comprises propylene and from about 5 to 25 wt % units derived from ethylene and/or a C 4 -C 10 α-olefin, and has a melting point less than about 105° C., a heat of fusion less than about 75 J/g, and a triad tacticity greater than about 75%; and
molding the coated substrate in a blow molding process in which the temperature of the mold is greater than about 135° C.
2. The process of claim 1 , wherein the plastic substrate is made of polyethylene terephthalate, and the temperature of the mold is greater than about 140° C.
3. The process of claim 2 , wherein the temperature of the mold is greater than about 145° C.
4. The process of claim 1 , wherein the coating composition has a static coefficient of friction less than or equal to about 0.55.
5. The process of claim 1 , wherein the coating composition has a kinetic coefficient of friction less than or equal to about 0.40.
6. The process of claim 1 , wherein the coating composition has two or more of the following properties:
a. a static coefficient of friction less than or equal to about 0.55;
b. a kinetic coefficient of friction less than or equal to about 0.40;
c. a Vicat softening temperature less than about 60° C.; or
d. a haze value less than or equal to about 60%.
7. The process of claim 1 , wherein the hydrocarbon resin has a glass transition temperature between about 35° C. and about 120° C., a Mw between about 100 g/mole and about 1000 g/mole, and a Mn between about 100 g/mole and about 500 g/mole.
8. The process of claim 1 , wherein the substrate is a bottle.
9. The process of claim 8 , wherein the bottle comprises polyethylene terephthalate.
10. The process of claim 1 , wherein the molding imparts one or more textural design details onto the coating composition, and wherein the one or more textural design details are retained by the coating composition after molding.
11. The process of claim 1 , wherein the coating composition is applied to at least a portion of the substrate by extrusion.
12. A process for forming a composite material, comprising:
applying a coating composition onto at least a portion of a plastic substrate;
wherein the coating composition is a polymer blend comprising from about 5 to about 15 wt % of a first propylene-based copolymer, from about 35 to about 80 wt % of a second propylene-based copolymer, and from 30 wt % to about 50 wt % of one or more hydrocarbon resins, wherein at least one propylene-based copolymer comprises propylene and from about 5 to 25 wt % units derived from ethylene and/or a C 4 -C 10 α-olefin, and has a melting point less than about 105° C., a heat of fusion less than about 75 J/g, and a triad tacticity greater than about 75%; and
molding the coated substrate in a blow molding process in which the temperature of the mold is greater than about 135° C.
13. The process of claim 12 , wherein the temperature of the mold is greater than about 140° C.
14. The process of claim 13 , wherein the plastic substrate is made of polyethylene terephthalate, and the temperature of the mold is greater than about 145° C.
15. The process of claim 12 , wherein the coating composition has a static coefficient of friction less than or equal to about 0.55.
16. The process of claim 12 , wherein the coating composition has a kinetic coefficient of friction less than or equal to about 0.40.
17. The process of claim 12 , wherein the hydrocarbon resin has a glass transition temperature between about 35° C. and about 120° C., a Mw between about 100 g/mole and about 1000 g/mole, and a Mn between about 100 g/mole and about 500 g/mole.
18. The process of claim 12 , wherein the substrate is a bottle.
19. The process of claim 18 , wherein the bottle comprises polyethylene terephthalate.
20. The process of claim 12 , wherein the molding imparts one or more textural design details onto the coating composition, wherein the one or more textural design details are retained by the coating composition after molding.
21. The process of claim 12 , wherein the coating composition is applied to at least a portion of the substrate by extrusion.
22. A process for forming a composite material, comprising:
applying a coating composition onto at least a portion of a plastic substrate; wherein the coating composition is a polymer blend comprising from about 50 to about 95 wt % of one or more propylene-based copolymers and from 30 wt % to about 50 wt % of one or more hydrocarbon resins, wherein at least one propylene-based copolymer comprises propylene and from about 5 to 25 wt % units derived from ethylene and/or a C 4 -C 10 α-olefin, and has a melting point less than about 105° C., a heat of fusion less than about 75 J/g, and a triad tacticity greater than about 75%; and
molding the coated substrate in a blow molding process in which the temperature of the mold is greater than about 135° C., and further in which a textural detail with resolution less than 1 mm is imparted to, and retained by, the coating composition on the substrate.
23. The process of claim 22 , wherein the coating composition consists essentially of the one or more propylene-based copolymers and the one or more hydrocarbon resins.
24. The process of claim 23 , wherein the coating composition comprises about 30 wt % of the one or more hydrocarbon resins.