Advanced supported liquid membranes for carbon dioxide control in extravehicular activity applications
There is disclosed a portable life support system with a component for removal of at least one selected gas. In an embodiment, the system includes a supported liquid membrane having a first side and a second side in opposition to one another, the first side configured for disposition toward an astronaut and the second side configured for disposition toward a vacuum atmosphere. The system further includes an ionic liquid disposed between the first side and the second side of the supported liquid membrane, the ionic liquid configured for removal of at least one selected gas from a region housing the astronaut adjacent the first side of the supported liquid membrane to the vacuum atmosphere adjacent the second side of the supported liquid membrane. Other embodiments are also disclosed.
1. A portable life support system for removal of at least one selected gas, the system comprising:
a supported liquid membrane having a first side and a second side in opposition to one another, the first side configured for disposition toward an astronaut and the second side configured for disposition toward a vacuum atmosphere; and
an ionic liquid disposed between the first side and the second side of the supported liquid membrane, the ionic liquid configured for removal of at least one selected gas from a region housing the astronaut adjacent the first side of the supported liquid membrane to the vacuum atmosphere adjacent the second side of the supported liquid membrane, the second side of the supported liquid membrane having a hydrophobic layer so as to prevent removal of the ionic liquid into the vacuum atmosphere, wherein the supported liquid membrane is configured to provide a higher affinity between carbon dioxide and the ionic liquid than a remainder of components of exhaled air, and wherein the supported liquid membrane has a selectivity for carbon dioxide over oxygen;
wherein the ionic liquid includes a functionalized amine group as the cation and at least one anion including tetrafluoroborate (BF 4 − ); and
wherein the primary amine functionalized cation is 1-(3-aminopropyl)-3-methylimidazolium (AP-Mim + ).
2. The system of claim 1 , wherein the at least one selected gas is carbon dioxide.
3. The system of claim 2 , wherein the supported liquid membrane with the ionic liquid is configured to control the region housing the astronaut to reduce an amount of carbon dioxide exposed to the astronaut.
4. The system of claim 2 , wherein the supported liquid membrane with the ionic liquid is selective for carbon dioxide over oxygen and nitrogen.
5. The system of claim 2 , wherein the supported liquid membrane with the ionic liquid is a continuous system for carbon dioxide removal.
6. The system of claim 2 , wherein the supported liquid membrane with the ionic liquid is configured to provide a permeation rate of carbon dioxide based on size and weight limitations for an astronaut.
7. The system of claim 1 , wherein the at least one selected gas is water vapor.
8. The system of claim 1 , wherein the supported liquid membrane with the ionic liquid is configured to control the region housing the astronaut to reduce an amount of water vapor exposed to the astronaut.
9. The system of claim 1 , wherein the supported liquid membrane with the ionic liquid is a continuous system for water vapor removal.
10. The system of claim 1 , wherein the at least one selected gas includes carbon dioxide and water vapor, wherein the component is configured for simultaneous removal of the carbon dioxide and the water vapor.
11. The system of claim 1 , wherein the supported liquid membrane with the ionic liquid is regenerable by exposure to the vacuum without a temperature change to the supported liquid membrane.
12. The system of claim 1 , wherein the supported liquid membrane with the ionic liquid has a zero vapor pressure, wherein the ionic liquid is prevented from evaporating to the vacuum.
13. The system of claim 1 , wherein the ionic liquid includes a functionalized amine group as the cation.
14. The system of claim 1 , wherein the ionic liquid cation includes a primary amine.
15. The system of claim 1 , wherein the ionic liquid cation includes a secondary amine.
16. The system of claim 1 , wherein the ionic liquid cation includes a tertiary amine.
17. The system of claim 16 , wherein the tertiary amine functionalized cation is 1-butyl-4-(N,N-dimethylamino)pyridinium (B-DMAPyr + ).
18. The system of claim 1 , wherein the supported liquid membrane is a hollow fiber form with an inside surface and an outside surface, the inside surface of the hollow fiber providing a first side and the outside surface of the hollow fiber providing a second side.
19. The system of claim 1 , wherein the portable life support system is a space suit.
20. The system of claim 1 , wherein the selectivity for carbon dioxide over oxygen is at least a threshold amount of 500.
21. The system of claim 1 , wherein the selectivity for carbon dioxide over oxygen is at least a threshold amount of 1300.